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- W3118889671 abstract "The effects of depositing Pd alloy nanoparticles (NPs) on an amine-functionalized Fe-metal organic framework (MOF; MIL-88B-NH2) were investigated, with the aim of developing a photo-switchable bifunctional catalyst for hydrogen storage/delivery mediated by CO2/formic acid (FA). The highly dispersed PdAg NPs promoted photocatalytic FA synthesis from CO2 under visible light and inhibited electron-hole recombination by efficiently trapping excited electrons. The release of H2 via the dehydrogenation of FA upon heating was efficiently catalyzed by the electron-rich Pd species generated by alloying with Ag. These Pd species acted as crucial active centers associated with amine-functionalized moieties in the linker groups of the Fe-MOF." @default.
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- W3118889671 date "2021-04-05" @default.
- W3118889671 modified "2023-09-25" @default.
- W3118889671 title "PdAg Nanoparticles Supported on an Amine-functionalized MOF as a Photo-switchable Catalyst for Hydrogen Storage/Delivery Mediated by CO2/Formic Acid" @default.
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- W3118889671 doi "https://doi.org/10.1246/cl.200905" @default.
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