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- W3118902484 abstract "Abstract The development of a sustainable catalytic system for red-light-induced photocatalysis is presented. The catalytic system consists of a helical carbenium ion-based organic photoredox catalyst (PC) that is capable of using low-energy red light (λmax = 640 nm) for both photooxidations and photoreductions. Its successful applications in the aerobic oxidative hydroxylation of arylboronic acids and in the oxidation of benzylic C(sp3)–H bonds (reductive quenching), as well as in dual transition-metal/organocatalyzed C–H arylations and intermolecular atom-transfer radical additions (oxidative quenching) provide further support for its role as a versatile and efficient organic PC. 1 Introduction 2 Red-Light-Induced Photocatalysis 3 Properties of N,N′-Dipropyl-1,13-dimethoxyquinacridinium Tetrafluoroborate 4 Two Proposed Representative Catalytic Cycles of [ n Pr-DMQA+][BF4 –] 5 Applications of [ n Pr-DMQA+][BF4 –] in Red-Light-Induced Photocatalysis 6 Conclusion" @default.
- W3118902484 created "2021-01-18" @default.
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- W3118902484 date "2020-10-12" @default.
- W3118902484 modified "2023-09-25" @default.
- W3118902484 title "Helical Carbenium Ion-Based Organic Photoredox Catalyst: A Versatile and Sustainable Option in Red-Light-Induced Reactions" @default.
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- W3118902484 doi "https://doi.org/10.1055/s-0040-1705942" @default.
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