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- W3119105928 abstract "Ammonia is among the available sustainable fuels for humans in the future. Electrochemical nitrogen fixation, which is a promising ammonia synthesis method, can achieve artificial N2 fixation at room temperature and pressure. We report that 5% Co4N/Co2C@rGO is a high-efficiency nitrogen reduction reaction electrocatalyst for ammonia synthesis under ambient conditions. The catalyst obtains high NH3 yield (24.12 μg h–1 mgcat–1) and Faradaic efficiency (24.97%) at −0.1 V (vs RHE) in 0.1 M HCl. The addition of graphene reduces CoN to Co2C and Co4N. A high ratio of Co–C bonds improves NRR performance. The excellent performance of the catalyst is attributed to the high proportion of pyridine N and pyrrole N. Data analysis results show that the NRR on the surface of Co4N adopts a favorable Mars–van Krevelen reaction mechanism. Moreover, the Co2C(101) crystal plane is more conducive to NRR." @default.
- W3119105928 created "2021-01-18" @default.
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- W3119105928 date "2021-01-12" @default.
- W3119105928 modified "2023-10-13" @default.
- W3119105928 title "Co<sub>4</sub>N/Co<sub>2</sub>C@rGO with Abundant Co–C and N–C Bonds as Highly Efficient Electrocatalyst for N<sub>2</sub> Reduction" @default.
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- W3119105928 doi "https://doi.org/10.1021/acssuschemeng.0c08332" @default.
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