FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3119463504> ?p ?o ?g. }

• W3119463504 endingPage "1232" @default.
• W3119463504 startingPage "1218" @default.
• W3119463504 abstract "Photodegradation of organic dyes over coordination polymer (CP) photocatalysts has become one of the effective strategies for the prevention and control of water pollution, in which the energy band structures manipulated by the ligand field of the catalytically active metal play extremely vital roles in enhancing the photocatalytic activity. To better rationalize the ligand-field function on the band structure, a series of six 2,4,6-tris(4-pyridyl)-1,3,5-triazine (tpt)-based Zn(II)-CPs have been hydrothermally prepared by transforming the types, numbers, and locations of the coordinative substitutes attached on benzene. All of these Zn(II)-CPs have been fully structurally and photophysically characterized and used as photocatalysts for methylene blue (MB) decontamination by UV light illumination. Single-crystal structural analyses reveal that isomeric 1,2,4 (H3L1)- and 1,3,5-benzenetricarboxylates (H3L2) have assembled the ternary system into the gridlike framework {[Zn(tpt)(HL1)]·H2O}n (1), ribbon-to-connector aligned sheet [Zn3(H2O)(tpt)2(L1)2]n (2), and hexagonal dimer based double layer [Zn3(H2O)2(tpt)(L2)2]n (3). 1,2,4,5-Tetrasubstituted phenyl and diphenyl coligands have assisted in honeycomb-shaped, pillared-layer, and cuboid-like frameworks via synergetic binding of carboxylate, sulfonate and hydroxyl moieties: {[Zn2(tpt)(H2L3)(L3)0.5]·0.5H2O}n (4, H4L3 = 2,5-dihydroxyltelephthalic acid), {[Zn2.5(tpt)(μ-OH)(L4)]·1.5H2O}n (5, H4L4 = 5-sulfobenzene-1,2,4-tricarboxylic acid), and {[Zn3(H2O)0.5(tpt)2(μ-OH)(L5)1.25]·5H2O}n (6, H4L5 = 3,3′-disulfonyl-4,4′-biphenyldicarboxylic acid). More significantly, the changeable donor surroundings around the Zn(II) ions have optimized the ligand-field geometries, giving rise to variable band gaps and band potentials. Resulting from the effective isolation and migration of the charge carriers and much stronger oxidizing ability of the valence band, the cuboid-shaped framework 6 has exhibited the best photodegradation activity toward the MB pollutant, up to 89% after 4 h UV illumination. These observations have systematically revealed the consequence of the ligand field on the CP photocatalysts in organic dye photodecomposition." @default.
• W3119463504 created "2021-01-18" @default.
• W3119463504 creator A5028498756 @default.
• W3119463504 creator A5030663922 @default.
• W3119463504 creator A5037416067 @default.
• W3119463504 creator A5044578288 @default.
• W3119463504 creator A5066572489 @default.
• W3119463504 creator A5075889094 @default.
• W3119463504 creator A5078559565 @default.
• W3119463504 creator A5082485253 @default.
• W3119463504 date "2021-01-14" @default.
• W3119463504 modified "2023-10-15" @default.
• W3119463504 title "Water-Stable Zn(II) Coordination Polymers Regulated by Polysubstituted Benzenes and Their Photocatalytic Performance toward Methylene Blue Degradation Dominated by Ligand-Field Effects" @default.
• W3119463504 cites W1141735954 @default.
• W3119463504 cites W1484977625 @default.
• W3119463504 cites W1982274402 @default.
• W3119463504 cites W1999937609 @default.
• W3119463504 cites W2025256923 @default.
• W3119463504 cites W2042397184 @default.
• W3119463504 cites W2060561896 @default.
• W3119463504 cites W2069025028 @default.
• W3119463504 cites W2104159074 @default.
• W3119463504 cites W2105249240 @default.
• W3119463504 cites W2166766376 @default.
• W3119463504 cites W2267223424 @default.
• W3119463504 cites W2299529061 @default.
• W3119463504 cites W2332402427 @default.
• W3119463504 cites W2332492714 @default.
• W3119463504 cites W2513063169 @default.
• W3119463504 cites W2517430690 @default.
• W3119463504 cites W2590955794 @default.
• W3119463504 cites W2607412255 @default.
• W3119463504 cites W2625755924 @default.
• W3119463504 cites W2786336035 @default.
• W3119463504 cites W2790057497 @default.
• W3119463504 cites W2793731839 @default.
• W3119463504 cites W2805870439 @default.
• W3119463504 cites W2885685805 @default.
• W3119463504 cites W2888601253 @default.
• W3119463504 cites W2889543900 @default.
• W3119463504 cites W2897239728 @default.
• W3119463504 cites W2902227562 @default.
• W3119463504 cites W2909630440 @default.
• W3119463504 cites W2917095908 @default.
• W3119463504 cites W2923842149 @default.
• W3119463504 cites W2924048087 @default.
• W3119463504 cites W2969429301 @default.
• W3119463504 cites W2977192079 @default.
• W3119463504 cites W2982665692 @default.
• W3119463504 cites W2983549902 @default.
• W3119463504 cites W2990894424 @default.
• W3119463504 cites W3002080239 @default.
• W3119463504 cites W3004083391 @default.
• W3119463504 cites W3005073129 @default.
• W3119463504 cites W3005479171 @default.
• W3119463504 cites W3024583416 @default.
• W3119463504 cites W3092636757 @default.
• W3119463504 doi "https://doi.org/10.1021/acs.cgd.0c01521" @default.
• W3119463504 hasPublicationYear "2021" @default.
• W3119463504 type Work @default.
• W3119463504 sameAs 3119463504 @default.
• W3119463504 citedByCount "22" @default.
• W3119463504 countsByYear W31194635042021 @default.
• W3119463504 countsByYear W31194635042022 @default.
• W3119463504 countsByYear W31194635042023 @default.
• W3119463504 crossrefType "journal-article" @default.
• W3119463504 hasAuthorship W3119463504A5028498756 @default.
• W3119463504 hasAuthorship W3119463504A5030663922 @default.
• W3119463504 hasAuthorship W3119463504A5037416067 @default.
• W3119463504 hasAuthorship W3119463504A5044578288 @default.
• W3119463504 hasAuthorship W3119463504A5066572489 @default.
• W3119463504 hasAuthorship W3119463504A5075889094 @default.
• W3119463504 hasAuthorship W3119463504A5078559565 @default.
• W3119463504 hasAuthorship W3119463504A5082485253 @default.
• W3119463504 hasConcept C115624301 @default.
• W3119463504 hasConcept C116569031 @default.
• W3119463504 hasConcept C161790260 @default.
• W3119463504 hasConcept C162847780 @default.
• W3119463504 hasConcept C170493617 @default.
• W3119463504 hasConcept C178790620 @default.
• W3119463504 hasConcept C185592680 @default.
• W3119463504 hasConcept C2777691172 @default.
• W3119463504 hasConcept C2781432337 @default.
• W3119463504 hasConcept C55493867 @default.
• W3119463504 hasConcept C65165184 @default.
• W3119463504 hasConcept C75473681 @default.
• W3119463504 hasConcept C8010536 @default.
• W3119463504 hasConceptScore W3119463504C115624301 @default.
• W3119463504 hasConceptScore W3119463504C116569031 @default.
• W3119463504 hasConceptScore W3119463504C161790260 @default.
• W3119463504 hasConceptScore W3119463504C162847780 @default.
• W3119463504 hasConceptScore W3119463504C170493617 @default.
• W3119463504 hasConceptScore W3119463504C178790620 @default.
• W3119463504 hasConceptScore W3119463504C185592680 @default.
• W3119463504 hasConceptScore W3119463504C2777691172 @default.
• W3119463504 hasConceptScore W3119463504C2781432337 @default.
• W3119463504 hasConceptScore W3119463504C55493867 @default.
• W3119463504 hasConceptScore W3119463504C65165184 @default.

• next