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• W3119585230 abstract "It is necessary to design a ligand that is compatible with the target molecule to optimally use the DNA-cleaving ability of metal complexes. In this study, we synthesized an optically active dinuclear ligand, (1R,1′R,2R,2′R)-N1,N1′-(anthracene-1,8-diylbis(methylene))bis(N2,N2-bis(pyridin-2-ylmethyl)cyclohexane-1,2-diamine) (R-ABDC, 4a) and its enantiomer (S-ABDC, 4b). We then prepared their Fe(II) complexes by mixing the ligand with FeSO4·7H2O in situ and investigated DNA-cleaving activities using plasmid DNA in the presence of excess sodium ascorbate at atmospheric conditions. The Fe(II) complexes efficiently cleaved DNA and selectively recognized two consecutive A and/or T sequences." @default.
• W3119585230 created "2021-01-18" @default.
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• W3119585230 date "2021-03-01" @default.
• W3119585230 modified "2023-09-23" @default.
• W3119585230 title "Design and synthesis of an anthranyl bridged optically active dinuclear iron(II)-ligand and evaluation of DNA-cleaving activity" @default.
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• W3119585230 doi "https://doi.org/10.1016/j.bmcl.2021.127782" @default.
• W3119585230 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33422608" @default.
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