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• W3119686501 abstract "Abstract This work provides the results of the spectroscopic, electrochemical, and photoelectrochemical study of the self-assembly in the systems consisting of (2,3,7,8,12,13,17,18-octaethylporphinato)cobalt(II) (CoOEP), (2,3,7,8,12,18-hexamethyl,13,17-diethyl,5-(4-pyridyl)porphinato)gold(III) chloride (ClAuP)/1′-N-methyl-2′-(pyridin-4-yl)pyrrolidino[3′,4′:1,2][60]fullerene (PyC60), and 1,2-dichlorobenzene/toluene as an electron donor, an acceptor, and a liquid medium, respectively. The results indicate axial coordination of electron acceptor functionalized by the pyridine units by cobalt(II) porphyrin with the donor-acceptor (ClAuP)2CoOEP/(PyC60)2CoOEP triad formation. The thermodynamic stability constant is (4.91 ± 1.10)×109 L2 mol−2 and (4.10 ± 1.14) ×1010 L2 mol−2 for ClAuP and PyC60, respectively. The formation of supramolecules was confirmed by UV, visible, IR, 1H NMR spectroscopy and cyclic voltammetry. DFT calculations (B3LYP+def2-SVP) detect octahedral geometry of the coordination center with the trans configuration of the axial ligands in the triads as well as the excited state calculations establish photoinduced electron transfer (PET). The jphavg value 266 μA cm−2 for the Ti|(ClAuP)2CoOEP|0.5 M Na2SO4|Pt system being 2–2.5 times higher compared with the precursors and slightly higher compared with (PyC60)2CoOEP shows that gold(III) porphyrin as an electron acceptor can be successfully used. The development of donor/acceptor platform selection strategy for the obtaining of photoactive supramolecules is an urgent task for future deriving of photovoltaic devices." @default.
• W3119686501 created "2021-01-18" @default.
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• W3119686501 date "2021-03-01" @default.
• W3119686501 modified "2023-10-03" @default.
• W3119686501 title "Self-organizing donor-acceptor assemblies of cobalt(II) porphyrin ligated with gold(III) porphyrin or fullero[60]pyrrolidine in liquid medium" @default.
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• W3119686501 doi "https://doi.org/10.1016/j.molliq.2021.115306" @default.
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