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- W3119787119 endingPage "328" @default.
- W3119787119 startingPage "328" @default.
- W3119787119 abstract "Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is regioselectively activated, affording an uncommon cyclometalated complex, called “rollover cyclometalated complex”. The key of the process is the internal rotation of the ligand, which occurs before the C–H bond activation and releases from coordination a donor atom. The new “rollover” ligand has peculiar properties, being a ligand with multiple personalities, no more a spectator in the reactivity of the complex. The main reason of this peculiarity is the presence of an uncoordinated donor atom (the one initially involved in the chelation), able to promote a series of reactions not available for classic cyclometalated complexes. The rollover reaction is highly regioselective, because the activated C–H bond is usually in a symmetric position with respect to the donor atom which detaches from the metal stating the rollover process. Due to this novel behavior, a series of potential applications have appeared in the literature, in fields such as catalysis, organic synthesis, and advanced materials." @default.
- W3119787119 created "2021-01-18" @default.
- W3119787119 creator A5023486226 @default.
- W3119787119 creator A5050323019 @default.
- W3119787119 date "2021-01-10" @default.
- W3119787119 modified "2023-10-18" @default.
- W3119787119 title "Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization" @default.
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