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- W3119986005 abstract "The reaction of the P4 butterfly compound [{Cp'''Fe(CO)2}2(μ,η1:1-P4)] (1, Cp''' = C5H2tBu3) towards various transition metal complexes is investigated. On the one hand, the reaction of 1 with [(PPh3)Au(tht)][PF6] (tht = tetrahydrothiophene) and [M(CO)4(nbd)] (M = Cr, Mo, W; nbd = norbornadiene) yields chelating complexes of the type [{Cp'''Fe(CO)2}2(µ3,η1:1:1:1-P4){Au(PPh3)}] (2d) and [{Cp'''Fe(CO)2}2(µ3,η1:1:1:1-P4){M(CO)4}] (2a-c, M = Cr, Mo, W), respectively, bearing intact P4 butterfly ligands with exceedingly small bite angles (ca. 65°). The reaction of 1 with Ag[PF6] even afforded the spiro complex [{(Cp'''Fe(CO)2)2(µ3,η1:1:1:1-P4)}2Ag][PF6] (3), in which the silver cation is coordinated in a distorted tetrahedral fashion by two P4 butterfly motifs. On the other hand, the reaction of 1 with the carbonyl containing Lewis acids Fe2(CO)9 or Co2(CO)8 leads to rearrangement yielding [{Cp'''Fe(CO)2}2{Co(CO)3}2(μ4,η2:2:1:1-P4)] (4), incorporating a folded cyclo-P4 scaffold, and [{Cp'''Fe(CO)2}2(µ4,η1:1:1:3-P4CO){Fe(CO)4}{Fe(CO)3}] (5), displaying a tetraphosphole structural motif obtained after carbonyl insertion, respectively. The products are comprehensively characterized by different spectroscopic methods as well as single crystal X-ray diffraction analysis and theoretical calculations." @default.
- W3119986005 created "2021-01-18" @default.
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- W3119986005 date "2021-04-01" @default.
- W3119986005 modified "2023-09-25" @default.
- W3119986005 title "The reactivity of the P4-butterfly ligand [{Cp'''Fe(CO)2}2(µ,η1:1-P4)] towards transition metal complexes: Coordination versus rearrangement" @default.
- W3119986005 cites W1565790616 @default.
- W3119986005 cites W1921179053 @default.
- W3119986005 cites W1973625876 @default.
- W3119986005 cites W1975036248 @default.
- W3119986005 cites W1975373771 @default.
- W3119986005 cites W1981528995 @default.
- W3119986005 cites W1983577054 @default.
- W3119986005 cites W1984206310 @default.
- W3119986005 cites W1992877981 @default.
- W3119986005 cites W1993091495 @default.
- W3119986005 cites W1993137144 @default.
- W3119986005 cites W2009041019 @default.
- W3119986005 cites W2011785644 @default.
- W3119986005 cites W2015769030 @default.
- W3119986005 cites W2019205927 @default.
- W3119986005 cites W2021067316 @default.
- W3119986005 cites W2025084555 @default.
- W3119986005 cites W2025886714 @default.
- W3119986005 cites W2027087575 @default.
- W3119986005 cites W2028298577 @default.
- W3119986005 cites W2029225109 @default.
- W3119986005 cites W2036647980 @default.
- W3119986005 cites W2038871458 @default.
- W3119986005 cites W2040274556 @default.
- W3119986005 cites W2044485440 @default.
- W3119986005 cites W2045332602 @default.
- W3119986005 cites W2047498401 @default.
- W3119986005 cites W2048498911 @default.
- W3119986005 cites W2048990493 @default.
- W3119986005 cites W2051625966 @default.
- W3119986005 cites W2052779491 @default.
- W3119986005 cites W2055594033 @default.
- W3119986005 cites W2070327350 @default.
- W3119986005 cites W2074023999 @default.
- W3119986005 cites W2078472219 @default.
- W3119986005 cites W2081778027 @default.
- W3119986005 cites W2091702998 @default.
- W3119986005 cites W2095647041 @default.
- W3119986005 cites W2102762913 @default.
- W3119986005 cites W2105282012 @default.
- W3119986005 cites W2116938372 @default.
- W3119986005 cites W2116942481 @default.
- W3119986005 cites W2129418872 @default.
- W3119986005 cites W2132916274 @default.
- W3119986005 cites W2143266554 @default.
- W3119986005 cites W2151079310 @default.
- W3119986005 cites W2152096802 @default.
- W3119986005 cites W2154626584 @default.
- W3119986005 cites W2155585261 @default.
- W3119986005 cites W2163950565 @default.
- W3119986005 cites W2165561651 @default.
- W3119986005 cites W2208066314 @default.
- W3119986005 cites W2291810066 @default.
- W3119986005 cites W2399565512 @default.
- W3119986005 cites W2412108804 @default.
- W3119986005 cites W2470230225 @default.
- W3119986005 cites W2477734162 @default.
- W3119986005 cites W2515908000 @default.
- W3119986005 cites W2613141100 @default.
- W3119986005 cites W2616818401 @default.
- W3119986005 cites W2744900908 @default.
- W3119986005 cites W2759415134 @default.
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- W3119986005 cites W2899622972 @default.
- W3119986005 cites W3041212774 @default.
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- W3119986005 doi "https://doi.org/10.1016/j.ica.2020.120234" @default.
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