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- W3120051337 abstract "In this report the initial results of a breakthrough and novel method to energetically connect the lowest-lying trans- (e0) and the gauche- (e1 and o1) states of Ethyl Alcohol. It is well known that the transitions between the trans- and gauche states in the ground internal rotational levels for OH torsion are forbidden due to symmetry considerations. This presented a considerable challenge to model the Hamiltonian for this molecule on a global basis and the most successful model required these two states to be treated separately as if the trans- and gauche- states represent two different molecules. The present communication reports for the very first time the method to energetically connect the trans- sub-states and the gauche sub-states with experimental accuracy. This would open a new vista to theoretical spectroscopists for a global model with both types of symmetry. The novel method has been conceived recently with the availability of high-resolution far-infrared (FIR) with very little noise. The spectroscopic idea behind the approach is presented here using a few representative states in the form of a rapid publication. The details are in progress and will be commutated in a future report." @default.
- W3120051337 created "2021-01-18" @default.
- W3120051337 creator A5074772756 @default.
- W3120051337 date "2021-05-01" @default.
- W3120051337 modified "2023-10-16" @default.
- W3120051337 title "A novel experimental method in connecting the trans- and gauche-states of Ethanol to high accuracy using synchrotron radiation spectrum through torsionally excited state transitions" @default.
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- W3120051337 doi "https://doi.org/10.1016/j.infrared.2020.103612" @default.
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