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- W3120113612 abstract "Abstract A simple synthesis of a library of novel C−N axially chiral iodoarenes is achieved in a three‐step synthesis from commercially available aniline derivatives. C−N axial chiral iodine reagents are rarely investigated in the hypervalent iodine arena. The potential of the novel chiral iodoarenes as organocatalysts for stereoselective oxidative transformations is assessed using the well explored, but challenging stereoselective α‐oxytosylation of ketones. All investigated reagents catalyse the stereoselective oxidation of propiophenone to the corresponding chiral α‐oxytosylated products with good stereochemical control. Using the optimised reaction conditions a wide range of products was obtained in generally good to excellent yields and with good enantioselectivities." @default.
- W3120113612 created "2021-01-18" @default.
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- W3120113612 date "2021-02-08" @default.
- W3120113612 modified "2023-10-12" @default.
- W3120113612 title "C−N Axial Chiral Hypervalent Iodine Reagents: Catalytic Stereoselective α‐Oxytosylation of Ketones" @default.
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- W3120113612 doi "https://doi.org/10.1002/chem.202005253" @default.
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