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• W3120348446 startingPage "7288" @default.
• W3120348446 abstract "Abstract The ligand H 3 L (6‐[3‐oxo‐3‐(2‐hydroxyphenyl)propionyl]pyridine‐2‐carboxylic acid), which exhibits two different coordination pockets, has been exploited to engender and study energy transfer (ET) in two dinuclear [Ln III Ln III ′] analogues of interest, [EuYb] and [NdYb]. Their structural and physical properties have been compared with newly synthesised analogues featuring no possible ET ([EuLu], [NdLu], and [GdYb]) and with the corresponding homometallic [EuEu] and [NdNd] analogues, which have been previously reported. Photophysical data suggest that ET between Eu III and Yb III does not occur to a significant extent, whereas emission from Yb III originates from sensitisation of the ligand. In contrast, energy migration seems to be occurring between the two Nd III centres in [NdNd], as well as in [NdYb], in which Yb III luminescence is thus, in part, sensitised by ET from Nd. This study shows the versatility of this molecular platform to further the investigation of lanthanide‐to‐lanthanide ET phenomena in defined molecular systems." @default.
• W3120348446 created "2021-01-18" @default.
• W3120348446 creator A5001464541 @default.
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• W3120348446 creator A5066443977 @default.
• W3120348446 date "2021-03-08" @default.
• W3120348446 modified "2023-10-08" @default.
• W3120348446 title "Accessing Lanthanide‐to‐Lanthanide Energy Transfer in a Family of Site‐Resolved [Ln^IIILn^III′] Heterodimetallic Complexes" @default.
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