FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3120368439> ?p ?o ?g. }

• W3120368439 endingPage "331" @default.
• W3120368439 startingPage "325" @default.
• W3120368439 abstract "Stereoselectivity, a distinctive characteristic of lipase (EC 3.1.1.3), refers to the ability to differentiate between enantiomeric positions (sn-1 and sn-3) in triacylglycerol (TAG). This property has been determined based on the time course of enantiomeric excess of diacylglycerol (DAG) considering several consecutive steps of lipase-catalyzed hydrolysis of TAG; however, this concept is insufficient to represent the true nature of lipases which are capable of hydrolyzing the sn-2 position of TAG under the condition acyl migration occurs. Here, we suggest “integral stereoselectivity” to capture the preference of lipases for all ester groups of both TAG and DAG, as a novel index of the stereochemistry of lipase. To determine integral stereoselectivity, we established an analytical system based on the chromatographic resolution of dioleoylglycerol (DO) enantiomers and regioisomers. DO enantiomers were derivatized with 4-nitrophenyl isocyanate, and subsequently, resolved by chiral-phase high-performance liquid chromatography–ultraviolet. Regioisomers of monooleoylglycerol and DO were analyzed by HPLC with an evaporative light-scattering detector. Time-course analysis of three model lipases involved in the hydrolysis of trioleoylglycerol validated the analytical system designed to determine the integral stereoselectivity. As an accurate indicator of lipase stereochemistry reflecting all hydrolysis steps, integral stereoselectivity can expedite the development of lipases with unique stereochemistry from agricultural sources and their application to the food industry." @default.
• W3120368439 created "2021-01-18" @default.
• W3120368439 creator A5020313355 @default.
• W3120368439 creator A5030914339 @default.
• W3120368439 creator A5033687355 @default.
• W3120368439 date "2021-01-05" @default.
• W3120368439 modified "2023-09-27" @default.
• W3120368439 title "Integral Stereoselectivity of Lipase Based on the Chromatographic Resolution of Enantiomeric/Regioisomeric Diacylglycerols" @default.
• W3120368439 cites W1485044764 @default.
• W3120368439 cites W1592367588 @default.
• W3120368439 cites W1964340580 @default.
• W3120368439 cites W1964542062 @default.
• W3120368439 cites W1969077614 @default.
• W3120368439 cites W1976806277 @default.
• W3120368439 cites W1980317108 @default.
• W3120368439 cites W1982396168 @default.
• W3120368439 cites W1983859254 @default.
• W3120368439 cites W1984020919 @default.
• W3120368439 cites W1989514233 @default.
• W3120368439 cites W2000790314 @default.
• W3120368439 cites W2008506205 @default.
• W3120368439 cites W2012709341 @default.
• W3120368439 cites W2067091077 @default.
• W3120368439 cites W2067289084 @default.
• W3120368439 cites W2069180449 @default.
• W3120368439 cites W2070930715 @default.
• W3120368439 cites W2076104132 @default.
• W3120368439 cites W2077054702 @default.
• W3120368439 cites W2078035828 @default.
• W3120368439 cites W2081186248 @default.
• W3120368439 cites W2087552451 @default.
• W3120368439 cites W2091202736 @default.
• W3120368439 cites W2094152940 @default.
• W3120368439 cites W2107278911 @default.
• W3120368439 cites W2121531429 @default.
• W3120368439 cites W2139838127 @default.
• W3120368439 cites W2314641164 @default.
• W3120368439 cites W2324472953 @default.
• W3120368439 cites W2900565310 @default.
• W3120368439 cites W3018409167 @default.
• W3120368439 cites W4300859091 @default.
• W3120368439 doi "https://doi.org/10.1021/acs.jafc.0c07430" @default.
• W3120368439 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33397094" @default.
• W3120368439 hasPublicationYear "2021" @default.
• W3120368439 type Work @default.
• W3120368439 sameAs 3120368439 @default.
• W3120368439 citedByCount "16" @default.
• W3120368439 countsByYear W31203684392021 @default.
• W3120368439 countsByYear W31203684392022 @default.
• W3120368439 countsByYear W31203684392023 @default.
• W3120368439 crossrefType "journal-article" @default.
• W3120368439 hasAuthorship W3120368439A5020313355 @default.
• W3120368439 hasAuthorship W3120368439A5030914339 @default.
• W3120368439 hasAuthorship W3120368439A5033687355 @default.
• W3120368439 hasConcept C129694887 @default.
• W3120368439 hasConcept C161790260 @default.
• W3120368439 hasConcept C178790620 @default.
• W3120368439 hasConcept C181199279 @default.
• W3120368439 hasConcept C181647583 @default.
• W3120368439 hasConcept C185592680 @default.
• W3120368439 hasConcept C195794163 @default.
• W3120368439 hasConcept C2779697368 @default.
• W3120368439 hasConcept C2780786110 @default.
• W3120368439 hasConcept C2780902120 @default.
• W3120368439 hasConcept C2900643 @default.
• W3120368439 hasConcept C36020004 @default.
• W3120368439 hasConcept C43617362 @default.
• W3120368439 hasConcept C486523 @default.
• W3120368439 hasConcept C71240020 @default.
• W3120368439 hasConcept C94412978 @default.
• W3120368439 hasConceptScore W3120368439C129694887 @default.
• W3120368439 hasConceptScore W3120368439C161790260 @default.
• W3120368439 hasConceptScore W3120368439C178790620 @default.
• W3120368439 hasConceptScore W3120368439C181199279 @default.
• W3120368439 hasConceptScore W3120368439C181647583 @default.
• W3120368439 hasConceptScore W3120368439C185592680 @default.
• W3120368439 hasConceptScore W3120368439C195794163 @default.
• W3120368439 hasConceptScore W3120368439C2779697368 @default.
• W3120368439 hasConceptScore W3120368439C2780786110 @default.
• W3120368439 hasConceptScore W3120368439C2780902120 @default.
• W3120368439 hasConceptScore W3120368439C2900643 @default.
• W3120368439 hasConceptScore W3120368439C36020004 @default.
• W3120368439 hasConceptScore W3120368439C43617362 @default.
• W3120368439 hasConceptScore W3120368439C486523 @default.
• W3120368439 hasConceptScore W3120368439C71240020 @default.
• W3120368439 hasConceptScore W3120368439C94412978 @default.
• W3120368439 hasFunder F4320322035 @default.
• W3120368439 hasFunder F4320334881 @default.
• W3120368439 hasIssue "1" @default.
• W3120368439 hasLocation W31203684391 @default.
• W3120368439 hasOpenAccess W3120368439 @default.
• W3120368439 hasPrimaryLocation W31203684391 @default.
• W3120368439 hasRelatedWork W1965313643 @default.
• W3120368439 hasRelatedWork W1989575556 @default.
• W3120368439 hasRelatedWork W2062712600 @default.
• W3120368439 hasRelatedWork W2066462312 @default.
• W3120368439 hasRelatedWork W2108980563 @default.
• W3120368439 hasRelatedWork W2197375360 @default.

• next