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• W3120492118 abstract "• Peripherally and non-peripherally tetra-substituted chalcone metallophthalocyanine derivatives were prepared. • Investigated their photophysical and photochemical properties. • Zinc(II) phthalocyanines exhibited highest singlet oxygen quantum yield values (Φ Δ = 0.56 for 5 and 0.39 for 9 ). In this study, the novel peripherally ( 5 – 7 ) and non-peripherally ( 9 – 11 ) metallo (zinc, magnesium and lead) phthalocyanine derivatives were synthesized from their ( E )-4-(4-bromo-2-(3-oxo-3- o -tolyprop-1-enyl)phenoxy) substituted phthalonitrile precursors ( 4 and 8 ). These novel phthalocyanine derivatives including chalcone groups were characterized by spectroscopic techniques such as FT-IR, UV–vis, 1 H NMR, 13 C NMR and MALDI-TOF mass spectra. In the next stage, the photophysical and photochemical properties of synthesized compounds were searched in DMSO which is not cause toxic effects at a certain concentration in biological applications. As a result of investigations, it was determined that phthalocyanine complexes did not demonstrate aggregation in DMSO solutions." @default.
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• W3120492118 date "2021-05-01" @default.
• W3120492118 modified "2023-10-17" @default.
• W3120492118 title "Synthesis of peripheral and non-peripheral substituted metallophthalocyanines containing (E)-3-(5-bromo-2-hydroxphenyl)-1-o-tolyprop-2-en-1-one: Investigation of the photophysical and photochemical properties" @default.
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• W3120492118 doi "https://doi.org/10.1016/j.saa.2021.119474" @default.
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