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• W3120553135 abstract "A four-temperature kinetic-theory approach for modeling vibrationally non-equilibrium carbon dioxide flows is developed. The model takes into account all kinds of vibrational–translational energy transitions and inter-mode vibrational energy exchange between symmetric, bending, and asymmetric CO2 modes. The key feature of the model is using the averaged state-resolved relaxation rates instead of conventional Landau–Teller expressions. Spatially homogeneous CO2 vibrational relaxation is studied using the state-to-state, new four-temperature and commonly used three-temperature models. Excellent agreement between four-temperature and state-to-state solutions is found, whereas using the three-temperature model with the Landau–Teller production rates leads to significant loss of accuracy. Numerical efficiency of various approaches is discussed as well as the ways for its improvement." @default.
• W3120553135 created "2021-01-18" @default.
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• W3120553135 date "2021-01-01" @default.
• W3120553135 modified "2023-10-05" @default.
• W3120553135 title "Four-temperature kinetic model for CO₂ vibrational relaxation" @default.
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• W3120553135 doi "https://doi.org/10.1063/5.0035171" @default.
• W3120553135 hasPublicationYear "2021" @default.
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