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• W3120664151 abstract "This research work deals with the diphenyl phosphate (DPP) detection in urine samples using a molecularly imprinted polymer (MIP) sensor and a voltammetric electronic tongue (VE-tongue). In this regard, gold nanoparticles (Au-NPs) and titanium dioxide (TiO2) were first designed onto a screen-printed carbon electrode (SPCE). Then, the sensor was fabricated by bulk-polymerizing methacrylic acid in the presence of DPP molecules as template. To achieve a sensor with optimal performance, crucial experimental parameters were well optimized. This sensor exhibits good linearity over a range of 0.1–24.3 ng/mL (R2 = 0.98) as well as high sensitivity (0.141 μA/ng.mL−1) and low detection limit (LOD =0.063 ng/mL). Moreover, suitable stability and selectivity were achieved with reproducibility and repeatability reached a RSD of 2.3 and 3.02 %, respectively. For the DPP determination in urine samples from nail polish users, the sensor reveals good results in concordance with spectrophotometry as reference method with a (RSD ≤ 4%). Secondly, qualitative analysis was performed by a VE-tongue combined with chemometrics to classify urine samples of nail polish users. Partial least squares (PLS) method supplied prediction models achieved from the both systems data with a regression coefficient (R = 0.99). Accordingly, the MIP sensor and VE-tongue could be viable electrochemical tools for cosmetic applications." @default.
• W3120664151 created "2021-01-18" @default.
• W3120664151 creator A5037408337 @default.
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• W3120664151 date "2021-04-01" @default.
• W3120664151 modified "2023-10-17" @default.
• W3120664151 title "An electrochemical sensor based on molecularly imprinted polymer conjointly with a voltammetric electronic tongue for quantitative diphenyl phosphate detection in urine samples from cosmetic product users" @default.
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• W3120664151 doi "https://doi.org/10.1016/j.snb.2021.129449" @default.
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