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- W3120710351 abstract "Three structurally different Cu(II), Co(II) and Ni(II) complexes constructed from a new single salamo-like ligand H 2 L and ancillary ligand 4,4′-bipy were synthesized and structurally characterized. • A new single salamo-like ligand H 2 L has been designed and synthesized. • The obtained three Cu(II), Co(II) and Ni(II) complexes possess different structures. • Theoretical calculations (Hirshfeld surfaces and DFT) and fluorescence properties of the three complexes are investigated. A new salamo-based ligand H 2 L was designed and synthesized, and its structurally different Cu(II), Co(II) and Ni(II) complexes based on ancillary ligand 4,4′-bipy were obtained. The Cu(II) complex has a mononuclear structure with the molecular formula of [Cu(L)], while the Cu(II) ion adopts a twisted four-coordinate quadrilateral geometric configuration. One dimensional chain-like supramolecular structure is formed by intermolecular interactions. In the Co(II) complex, there is a dimer structure and the molecular formula is [Co 2 (L) 2 (4,4′-bipy)]. The Co(II) ions possess five-coordinated trigonometric bipyramid geometric configurations. A two-dimensional layered supramolecular structure is formed by intermolecular interactions. The Ni(II) complex has a one-dimensional polymer structure and its molecular formula is [Ni(L)(4,4′-bipy)] n ·nEtOH·nAce. The Ni(II) ions have six-coordinated octahedron geometric configurations. Through the intermolecular interactions, a three-dimensional supramolecular structure is formed. The ligand H 2 L and its three complexes were studied in detail by IR, UV–Vis and emissive spectra. The short-range interactions in the Cu(II), Co(II) and Ni(II) complexes were calculated by Hirshfeld surfaces analyses. The molecular orbital energy levels and molecular stability were analyzed by DFT calculations." @default.
- W3120710351 created "2021-01-18" @default.
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- W3120710351 date "2021-04-01" @default.
- W3120710351 modified "2023-10-03" @default.
- W3120710351 title "Exploring coordination behaviors, structural characterizations and theoretical calculations of structurally different Cu(II), Co(II) and Ni(II) emissive complexes constructed from a salamo-based ligand and 4,4′-bipy" @default.
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- W3120710351 doi "https://doi.org/10.1016/j.ica.2021.120247" @default.
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