Matches in SemOpenAlex for { <https://semopenalex.org/work/W3120717228> ?p ?o ?g. }
- W3120717228 endingPage "2157" @default.
- W3120717228 startingPage "2135" @default.
- W3120717228 abstract "A concise and diastereoselective construction of the ABCD ring system of spirochensilide A is described. The key steps of this synthesis are a semipinacol rearrangement reaction to stereoselectively construct the AB ring system bearing two vicinal quaternary chiral centers and a Co-mediated Pauson–Khand reaction to form the spiro-based bicyclic CD ring system. This chemistry leads to the stereoselective synthesis of 13(R)-demethyl spirochensilide A, paving the way for the first asymmetric total synthesis of (−)-spirochensilide A." @default.
- W3120717228 created "2021-01-18" @default.
- W3120717228 creator A5002757725 @default.
- W3120717228 creator A5008920624 @default.
- W3120717228 creator A5009318195 @default.
- W3120717228 creator A5027083151 @default.
- W3120717228 creator A5030780941 @default.
- W3120717228 creator A5048055430 @default.
- W3120717228 creator A5072119048 @default.
- W3120717228 creator A5077802694 @default.
- W3120717228 creator A5082282744 @default.
- W3120717228 creator A5082778481 @default.
- W3120717228 date "2021-01-12" @default.
- W3120717228 modified "2023-10-14" @default.
- W3120717228 title "Asymmetric Total Synthesis of (−)-Spirochensilide A, Part 1: Diastereoselective Synthesis of the ABCD Ring and Stereoselective Total Synthesis of 13(<i>R</i>)-Demethyl Spirochensilide A" @default.
- W3120717228 cites W106803371 @default.
- W3120717228 cites W1519434515 @default.
- W3120717228 cites W1897111838 @default.
- W3120717228 cites W1897874172 @default.
- W3120717228 cites W1901902082 @default.
- W3120717228 cites W1965980597 @default.
- W3120717228 cites W1970892257 @default.
- W3120717228 cites W1972353936 @default.
- W3120717228 cites W1974772748 @default.
- W3120717228 cites W1976316723 @default.
- W3120717228 cites W1976898246 @default.
- W3120717228 cites W1985104693 @default.
- W3120717228 cites W1988262892 @default.
- W3120717228 cites W1991096030 @default.
- W3120717228 cites W1995435511 @default.
- W3120717228 cites W1995685869 @default.
- W3120717228 cites W1997871522 @default.
- W3120717228 cites W2008023238 @default.
- W3120717228 cites W2014783438 @default.
- W3120717228 cites W2018615626 @default.
- W3120717228 cites W2019415076 @default.
- W3120717228 cites W2023645786 @default.
- W3120717228 cites W2025590935 @default.
- W3120717228 cites W2025670799 @default.
- W3120717228 cites W2025825696 @default.
- W3120717228 cites W2026983146 @default.
- W3120717228 cites W2028212868 @default.
- W3120717228 cites W2029526231 @default.
- W3120717228 cites W2030923091 @default.
- W3120717228 cites W2036104373 @default.
- W3120717228 cites W2036357016 @default.
- W3120717228 cites W2038377704 @default.
- W3120717228 cites W2039563177 @default.
- W3120717228 cites W2041726370 @default.
- W3120717228 cites W2043853158 @default.
- W3120717228 cites W2045624618 @default.
- W3120717228 cites W2046143876 @default.
- W3120717228 cites W2050293242 @default.
- W3120717228 cites W2053956745 @default.
- W3120717228 cites W2058233843 @default.
- W3120717228 cites W2058623521 @default.
- W3120717228 cites W2064942112 @default.
- W3120717228 cites W2066965580 @default.
- W3120717228 cites W2071493717 @default.
- W3120717228 cites W2080849149 @default.
- W3120717228 cites W2082853057 @default.
- W3120717228 cites W2086189875 @default.
- W3120717228 cites W2086404667 @default.
- W3120717228 cites W2088499259 @default.
- W3120717228 cites W2092408277 @default.
- W3120717228 cites W2092587054 @default.
- W3120717228 cites W2094180759 @default.
- W3120717228 cites W2094518763 @default.
- W3120717228 cites W2097960211 @default.
- W3120717228 cites W2107154647 @default.
- W3120717228 cites W2134594140 @default.
- W3120717228 cites W2150765592 @default.
- W3120717228 cites W2155429076 @default.
- W3120717228 cites W2161749219 @default.
- W3120717228 cites W2165840926 @default.
- W3120717228 cites W2239949517 @default.
- W3120717228 cites W2298200895 @default.
- W3120717228 cites W2298782686 @default.
- W3120717228 cites W2314160382 @default.
- W3120717228 cites W2314681547 @default.
- W3120717228 cites W2316079563 @default.
- W3120717228 cites W2318715057 @default.
- W3120717228 cites W2319208778 @default.
- W3120717228 cites W2320201446 @default.
- W3120717228 cites W2320363248 @default.
- W3120717228 cites W2323745529 @default.
- W3120717228 cites W2325096660 @default.
- W3120717228 cites W2342610272 @default.
- W3120717228 cites W2410795914 @default.
- W3120717228 cites W2411021036 @default.
- W3120717228 cites W2507751125 @default.
- W3120717228 cites W2790651003 @default.
- W3120717228 cites W2889579662 @default.
- W3120717228 cites W2890854480 @default.
- W3120717228 cites W2896322248 @default.
- W3120717228 cites W2916302988 @default.
- W3120717228 cites W2949528699 @default.
- W3120717228 cites W2949720619 @default.