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- W3120751768 abstract "The recent development of liquid cell (scanning) transmission electron microscopy (LC-(S)TEM) has opened the unique possibility of studying the chemical behavior of nanomaterials down to the nanoscale in a liquid environment. Here, we show that the chemically induced etching of three different types of silica-based silica nanoparticles can be reliably studied at the single particle level using LC-(S)TEM with a negligible effect of the electron beam, and we demonstrate this method by successfully monitoring the formation of silica-based heterogeneous yolk–shell nanostructures. By scrutinizing the influence of electron beam irradiation, we show that the cumulative electron dose on the imaging area plays a crucial role in the observed damage and needs to be considered during experimental design. Monte-Carlo simulations of the electron trajectories during LC-(S)TEM experiments allowed us to relate the cumulative electron dose to the deposited energy on the particles, which was found to significantly alter the silica network under imaging conditions of nanoparticles. We used these optimized LC-(S)TEM imaging conditions to systematically characterize the wet etching of silica and metal(oxide)–silica core–shell nanoparticles with cores of gold and iron oxide, which are representative of many other core–silica–shell systems. The LC-(S)TEM method reliably reproduced the etching patterns of Stöber, water-in-oil reverse microemulsion (WORM), and amino acid-catalyzed silica particles that were reported before in the literature. Furthermore, we directly visualized the formation of yolk–shell structures from the wet etching of Au@Stöber silica and Fe3O4@WORM silica core–shell nanospheres." @default.
- W3120751768 created "2021-01-18" @default.
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- W3120751768 date "2021-01-05" @default.
- W3120751768 modified "2023-09-27" @default.
- W3120751768 title "<i>In Situ</i> Study of the Wet Chemical Etching of SiO<sub>2</sub> and Nanoparticle@SiO<sub>2</sub> Core–Shell Nanospheres" @default.
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- W3120751768 cites W1975663362 @default.
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- W3120751768 cites W2047898814 @default.
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- W3120751768 cites W2099049147 @default.
- W3120751768 cites W2099966776 @default.
- W3120751768 cites W2100334428 @default.
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- W3120751768 cites W2330656417 @default.
- W3120751768 cites W2331238623 @default.
- W3120751768 cites W2346030527 @default.
- W3120751768 cites W2416006905 @default.
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- W3120751768 cites W2530665662 @default.
- W3120751768 cites W2560590363 @default.
- W3120751768 cites W2563986004 @default.
- W3120751768 cites W2577983863 @default.
- W3120751768 cites W2591713154 @default.
- W3120751768 cites W2606166721 @default.
- W3120751768 cites W2606903347 @default.
- W3120751768 cites W2739122926 @default.
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- W3120751768 cites W2801148178 @default.
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- W3120751768 doi "https://doi.org/10.1021/acsanm.0c02771" @default.
- W3120751768 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7976607" @default.
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- W3120751768 hasPublicationYear "2021" @default.
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