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- W3120793637 abstract "To explore the natural resources as sustainable precursors offers a family of green materials. The use of bio-waste precursors especially the remaining from food processing is a scalable, highly abundant, and cost-effective strategy. Exploring waste materials is highly important especially for new materials discovery in emerging energy storage technologies such as lithium sulfur batteries (LSBs). Herein, waste milk powder is carbonized and constructed as the sulfur host with the hollow micro-/mesoporous framework, and the resulting carbonized milk powder and sulfur (CMP/S) composites are employed as cathodes for LSBs. It is revealed that the hollow micro-/mesoporous CMP/S framework can not only accommodate the volume expansion but also endow smooth pathways for the fast diffusion of electrons and Li-ions, leading to both high capacity and long cycling stability. The CMP/S composite electrode with 56 wt% loaded sulfur exhibits a remarkable initial capacity of 1596 mAh g−1 at 0.1 C, corresponding to 95% of the theoretical capacity. Even at a rate of 1 C, it maintains a high capacity of 730 mAh g−1 with a capacity retention of 72.6% after 500 cycles, demonstrating a very low capacity fading of only 0.05% per cycle. Importantly, the Coulombic efficiency is always higher than 96% during all the cycles. The only used source material is expired waste milk powders in our proposal. We believe that this “trash to treasure” approach will open up a new way for the utilization of waste material as environmentally safe and high performance electrodes for advanced LSBs." @default.
- W3120793637 created "2021-01-18" @default.
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- W3120793637 date "2022-10-01" @default.
- W3120793637 modified "2023-09-28" @default.
- W3120793637 title "Carbonized waste milk powders as cathodes for stable lithium–sulfur batteries with ultra-large capacity and high initial coulombic efficiency" @default.
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- W3120793637 doi "https://doi.org/10.1016/j.gee.2021.01.007" @default.
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