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• W3120997575 abstract "Highly efficient light-harvesting systems with the sequential energy transfer process are significant for utilizing solar energy in photosynthesis. Herein, we report a quadrilateral platinum(II) metallacycle containing tetraphenylethylene (M1) as a light-harvesting platform. The M1 assembly serves as an ideal donor because of the aggregation-induced emission (AIE) effect, realizing two-step sequential energy transfer from the M1 assembly to eosin Y (ESY) and then to sulforhodamine (SR101) with high efficiency. ESY was used as a bridge in a relay mode during this process. To better mimic natural photosynthesis, the M1-ESY-SR101 system was utilized as photochemical catalysis for alkylation of C-H bonds in aqueous solution, showing enhanced catalytic activity as compared with the M1-ESY system or ESY/SR101 alone." @default.
• W3120997575 created "2021-01-18" @default.
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• W3120997575 date "2021-01-15" @default.
• W3120997575 modified "2023-10-01" @default.
• W3120997575 title "Artificial Light-Harvesting Metallacycle System with Sequential Energy Transfer for Photochemical Catalysis" @default.
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• W3120997575 doi "https://doi.org/10.1021/jacs.0c12522" @default.
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• W3120997575 hasPublicationYear "2021" @default.
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