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- W3121365469 abstract "Abstract A broad variety of unactivated acyclic and alicyclic substrates cleanly undergo site‐selective alkenylation of unactivated C(sp 3 )−H bonds with 1,2‐bis(phenylsulfonyl)ethene in the presence of persulfate. This simple transformation furnishes ( E )‐2‐alkylvinylphenylsulfones in up to 88 % yield. In contrast with the previously reported decatungstate protocol, the current method is applicable to alkenylation of sterically hindered C−H bonds. This important advantage significantly broadens the substrate scope, and is attributed to the compact size of the sulfate radical employed in the C−H activation and cleavage." @default.
- W3121365469 created "2021-02-01" @default.
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- W3121365469 date "2020-12-14" @default.
- W3121365469 modified "2023-10-18" @default.
- W3121365469 title "Site‐Selective Alkenylation of Unactivated C(sp <sup>3</sup> )−H Bonds Mediated by Compact Sulfate Radical" @default.
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- W3121365469 doi "https://doi.org/10.1002/ange.202011992" @default.
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