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- W3121514881 abstract "The bonding properties of the dihalogenophosphenium cations, PX2(+), X = F, Cl, Br, I, are evaluated by relativistic effective core potential calculations with a DZP basis set. Our investigations include an analysis of the singlet-triplet energy separation in the cations and the determination of the relative cation and anion stabilities in the gas phase, via corresponding group transfer reactions. A comparison is made with other stabilized, previously reported low-coordinated pi-bonded phosphorus cations. (C) 1998 Elsevier Science B.V." @default.
- W3121514881 created "2021-02-01" @default.
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- W3121514881 date "2010-04-28" @default.
- W3121514881 modified "2023-09-27" @default.
- W3121514881 title "On the electronic structure of dihalogenophosphenium cations" @default.
- W3121514881 hasPublicationYear "2010" @default.
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