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- W3121717713 endingPage "1656" @default.
- W3121717713 startingPage "1648" @default.
- W3121717713 abstract "Despite the excellent mechanical and electrical performance of MXene–polymer nanocomposites, methods for producing these materials on a larger scale are limited by low-yielding, delaminated, MXene suspensions that are typically employed for their synthesis. Moreover, the hydrophilicity of MXenes restricts the production of well-dispersed nanocomposites with many polymer matrices. In this contribution, we address such limitations and report, for the first time, a simple method to covalently modify multilayered Ti3C2Tz MXenes with isocyanates, which enables their successful dispersion within a hydrophobic thiourethane matrix. The efficacy of our covalent modification was determined to yield high levels of surface grafts and suggests quantitative conversion of the oxygen-containing terminations. In situ-polymerized thiourethane “click” matrices were used to demonstrate the utility of this modification for accessing well-dispersed nanocomposites under ambient conditions. The ease of producing modified, multilayered, MXenes at scale and the availability of a wide variety of isocyanates render this method scalable and highly modular. Furthermore, the reported isocyanate treatment was found to be a valuable tool for easily quantifying the concentration of reactive (oxygen-containing) terminations on MXene surfaces." @default.
- W3121717713 created "2021-02-01" @default.
- W3121717713 creator A5001337097 @default.
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- W3121717713 creator A5065171840 @default.
- W3121717713 creator A5079803806 @default.
- W3121717713 creator A5091603830 @default.
- W3121717713 date "2021-01-22" @default.
- W3121717713 modified "2023-10-18" @default.
- W3121717713 title "Well-Dispersed Nanocomposites Using Covalently Modified, Multilayer, 2D Titanium Carbide (MXene) and In-Situ “Click” Polymerization" @default.
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