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• W3121740993 abstract "Abstract The combination of Co(III) and Dy(III) with a compartmental Schiff base ligand (H 3 L=3‐[(2‐Hydroxy‐3‐methoxy‐benzylidene)‐amino]‐propane‐1,2‐diol), presenting three different coordinating pockets, has allowed the synthesis of two novel Co(III)−Dy(III) complexes: [Co 2 Dy(HL) 4 ]NO 3 ⋅ 2CH 3 CN ( 1 ), a rare example of trinuclear linear Co III 2 Dy III complex (and the first with slow relaxation of magnetization in absence of a DC field) and [Co 2 Dy 2 (μ 3 −OH) 2 (HL) 2 (OAc) 6 ] ⋅ 4.6H 2 O ( 2 ), the first tetranuclear Co III 2 Dy III 2 cluster with a rhomb‐like structure where the Co(III) ions are connected along the short diagonal of the rhomb. 1 presents two different relaxation processes: a fast relaxation dominated by Quantum tunnelling (QT) and a slow relaxation with an energy barrier of 40 K. 2 shows two close relaxation processes without applied DC fields that follow QT and Orbach mechanisms whereas for H DC =500 Oe, the QT is cancelled and a direct term appears. Here we present the synthesis, X‐ray structure and magnetic characterization of these two Co(III)−Dy(III) single‐ion/molecule magnets." @default.
• W3121740993 created "2021-02-01" @default.
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• W3121740993 date "2021-02-22" @default.
• W3121740993 modified "2023-10-17" @default.
• W3121740993 title "Slow Magnetic Relaxation in a Co₂Dy Trimer and a Co₂Dy₂ Tetramer" @default.
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• W3121740993 doi "https://doi.org/10.1002/asia.202001468" @default.
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