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- W3123025186 abstract "The synthesis of (±)-epi-jungianol was successfully carried out by the gold(I)-catalyzed propargyl Claisen rearrangement/hydroarylation cascade reaction of suitably substituted propargyl vinyl ethers as the key step to form the indane skeleton. Two routes were compared, which involved substrates with a different degree of substitution on the vinyl moiety. The one based on a propargyl vinyl ether bearing an unsubstituted vinyl moiety, despite entailing two additional steps, provided the final compound in a higher overall yield. A method for the preparation of acid sensitive propargyl vinyl ethers with an α-alkyl-substituted vinyl moiety and their reactivity under gold catalysis is also reported." @default.
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- W3123025186 date "2021-02-12" @default.
- W3123025186 modified "2023-10-18" @default.
- W3123025186 title "Synthesis of (±)‐ <i>epi</i> ‐Jungianol by the Gold(I)‐Catalyzed Propargyl Claisen Rearrangement/Hydroarylation Cascade Reaction of Propargyl Vinyl Ethers" @default.
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- W3123025186 doi "https://doi.org/10.1002/ejoc.202001555" @default.
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