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- W3123078204 endingPage "109965" @default.
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- W3123078204 abstract "The yolk-shell structure of [email protected]@C anode for lithium ion batteries with Chito-oligosaccharide (COS) as carbon and nitrogen source was successfully prepared by using a newly designed method. As a low-molecular-weight precursor, COS is completely soluble in an aqueous solution to make the composite more homogeneous. The COS derived carbon has a higher porosity than macromolecules derived carbon, providing reliable channels for ions to shuttle. In addition, amino groups from COS effectually promote the wettability of electrode interface. For the yolk-shell structure of [email protected]@C composite, the outer carbon shell is not only conducive to the rapid transmission of electrons and lithium ions, but also to the reduction of charge transfer resistance and effective protection of the silicon core ball from electrolyte corrosion. Furthermore, the void layer between silicon core and carbon shell can adapt to huge volume expansion of Si and stabilize the electrode structure. Therefore, [email protected]@C exhibits superior cycle stability and high rate performance. At a current density of 420 mA g−1, after 200 cycles, the [email protected]@C maintains a high capacity of 1038.5 mAh g−1. In this experiment, the innovative synthesis of a unique yolk-shell structure of [email protected] composites is an effective way to obtain high-performance anode materials." @default.
- W3123078204 created "2021-02-01" @default.
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- W3123078204 date "2021-05-01" @default.
- W3123078204 modified "2023-10-11" @default.
- W3123078204 title "Yolk-shell Si@void@C composite with Chito-oligosaccharide as a C–N precursor for high capacity anode in lithium-ion batteries" @default.
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- W3123078204 doi "https://doi.org/10.1016/j.jpcs.2021.109965" @default.
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