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• W3123449506 abstract "We have established detailed magnetoelectric phase diagrams of (Eu$_{0.595}$Y$_{0.405}$)$_{1-x}$Tb$_x$MnO$_3$ ($0 le x le 1$) and (Eu,Y)$_{1-x}$Gd$_x$MnO$_3$ ($0 le x le 0.69$), whose average ionic radii of $R$-site ($R$: rare earth) cations are equal to that of Tb$^{3+}$, in order to reveal the effect of rare earth 4$f$ magnetic moments on the magnetoelectric properties. In spite of the same $R$-site ionic radii, the magnetoelectric properties of the two systems are remarkably different from each other. A small amount of Tb substitution on $R$ sites ($x sim 0.2$) totally destroys ferroelectric polarization along the a axis ($P_a$), and an increase in Tb concentration stabilizes the $P_c$ phase. On the other hand, Gd substitution ($x sim 0.2$) extinguishes the $P_c$ phase, and slightly suppresses the $P_a$ phase. These results demonstrate that the magnetoelectric properties of $R$MnO$_3$ strongly depend on the characteristics of the rare earth 4$f$ moments." @default.
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• W3123449506 date "2010-05-15" @default.
• W3123449506 modified "2023-09-25" @default.
• W3123449506 title "The Effect of<i>f</i>–<i>d</i>Magnetic Coupling in Multiferroic<i>R</i>MnO₃Crystals" @default.
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• W3123449506 doi "https://doi.org/10.1143/jpsj.79.054704" @default.
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