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- W31235701 abstract "ABSTRACT The paper describes impedance data obtained on 316 stainless steel during pit initiation studies. The complex impedance response can be modelled using an equivalent ciruit incorporating two adsorbed intermediates. This may represent either electrocrystallisation phenomena or the adsorption of species associated with dissolution and repassivation processes. The modelling data is discussed in terms of film breakdown, metal dissolution and film formation. It is suggested that pit initiation is first a process of film rupture due to adsorption of chloride ions on the film. Above the pitting potential the repassivation is then inhibited by a chloro-complex intermediate." @default.
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- W31235701 date "1983-01-01" @default.
- W31235701 modified "2023-09-26" @default.
- W31235701 title "INITIAL STAGES OF FILM BREAKDOWN ON PASSIVE AUSTENITIC STAINLESS STEEL IN 3% SODIUM CHLORIDE" @default.
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- W31235701 doi "https://doi.org/10.1016/b978-0-444-42252-1.50059-x" @default.
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