Matches in SemOpenAlex for { <https://semopenalex.org/work/W3124202226> ?p ?o ?g. }
- W3124202226 endingPage "60" @default.
- W3124202226 startingPage "53" @default.
- W3124202226 abstract "Converting formate to methanol is an economic strategy to expand the production of formate from CO2 electro-reduction while satisfying the increasing market demand for methanol. For selective hydrogenation of formate esters to methanol, it is crucial to understand how the interaction between metal catalyst and support affects catalytic performance. In this paper, ZrO2 was employed as the support to promote the Cu catalysts’ activity and selectivity in liquid-phase hydrogenation of ethyl formate. To maximize the production yield of methanol, various catalyst properties and reaction condition were investigated. Under the optimized conditions, i.e., 160 °C and 400 psi H2, ∼ 53 % of methanol were yielded from the hydrogenation of ethyl formate in anhydrous ethanol solvent over the 20 wt% Cu/ZrO2 catalyst. The calcination temperature in the catalyst synthesis had profound effects on the Cu valence states, the structure of the ZrO2 support, and the interactions between Cu and ZrO2. A variety of characterization tools, including XRD, XPS, and HRTEM, were used to elucidate the structure-activity relationship of the Cu/ZrO2 catalysts. These findings will facilitate the next-generation catalyst design and elucidate the synergistic interaction between Cu and ZrO2 that promotes ester hydrogenation reactions." @default.
- W3124202226 created "2021-02-01" @default.
- W3124202226 creator A5045197865 @default.
- W3124202226 creator A5048720856 @default.
- W3124202226 creator A5057979028 @default.
- W3124202226 creator A5071915774 @default.
- W3124202226 creator A5077647443 @default.
- W3124202226 creator A5083689063 @default.
- W3124202226 creator A5085662800 @default.
- W3124202226 date "2021-08-01" @default.
- W3124202226 modified "2023-09-23" @default.
- W3124202226 title "Synergistic interaction between Cu and ZrO2 promotes ethyl formate hydrogenation to produce methanol" @default.
- W3124202226 cites W1161328857 @default.
- W3124202226 cites W1490594981 @default.
- W3124202226 cites W1627978401 @default.
- W3124202226 cites W1763850145 @default.
- W3124202226 cites W1966534611 @default.
- W3124202226 cites W1989015309 @default.
- W3124202226 cites W1989096179 @default.
- W3124202226 cites W1998453884 @default.
- W3124202226 cites W2000286744 @default.
- W3124202226 cites W2007013884 @default.
- W3124202226 cites W2008788554 @default.
- W3124202226 cites W2009411714 @default.
- W3124202226 cites W2017123413 @default.
- W3124202226 cites W2020561818 @default.
- W3124202226 cites W2020785690 @default.
- W3124202226 cites W2020793815 @default.
- W3124202226 cites W2021651200 @default.
- W3124202226 cites W2022566650 @default.
- W3124202226 cites W2027898383 @default.
- W3124202226 cites W2034924684 @default.
- W3124202226 cites W2048174884 @default.
- W3124202226 cites W2050158761 @default.
- W3124202226 cites W2067686040 @default.
- W3124202226 cites W2077468110 @default.
- W3124202226 cites W2085406388 @default.
- W3124202226 cites W2090202376 @default.
- W3124202226 cites W2110154495 @default.
- W3124202226 cites W2140156540 @default.
- W3124202226 cites W2145466975 @default.
- W3124202226 cites W2157740295 @default.
- W3124202226 cites W2191300968 @default.
- W3124202226 cites W2217718435 @default.
- W3124202226 cites W2296880544 @default.
- W3124202226 cites W2319615030 @default.
- W3124202226 cites W2320344252 @default.
- W3124202226 cites W2323045099 @default.
- W3124202226 cites W2330976036 @default.
- W3124202226 cites W2343511514 @default.
- W3124202226 cites W2476521223 @default.
- W3124202226 cites W2503176236 @default.
- W3124202226 cites W2531985189 @default.
- W3124202226 cites W2579891120 @default.
- W3124202226 cites W2588128341 @default.
- W3124202226 cites W2589549881 @default.
- W3124202226 cites W2606578874 @default.
- W3124202226 cites W2621019167 @default.
- W3124202226 cites W2621876460 @default.
- W3124202226 cites W2625918461 @default.
- W3124202226 cites W2742520121 @default.
- W3124202226 cites W2765570278 @default.
- W3124202226 cites W2790006205 @default.
- W3124202226 cites W2884737359 @default.
- W3124202226 cites W2891376110 @default.
- W3124202226 cites W2929651773 @default.
- W3124202226 cites W3097099078 @default.
- W3124202226 cites W4247382714 @default.
- W3124202226 cites W4252472783 @default.
- W3124202226 doi "https://doi.org/10.1016/j.cattod.2020.12.027" @default.
- W3124202226 hasPublicationYear "2021" @default.
- W3124202226 type Work @default.
- W3124202226 sameAs 3124202226 @default.
- W3124202226 citedByCount "5" @default.
- W3124202226 countsByYear W31242022262022 @default.
- W3124202226 countsByYear W31242022262023 @default.
- W3124202226 crossrefType "journal-article" @default.
- W3124202226 hasAuthorship W3124202226A5045197865 @default.
- W3124202226 hasAuthorship W3124202226A5048720856 @default.
- W3124202226 hasAuthorship W3124202226A5057979028 @default.
- W3124202226 hasAuthorship W3124202226A5071915774 @default.
- W3124202226 hasAuthorship W3124202226A5077647443 @default.
- W3124202226 hasAuthorship W3124202226A5083689063 @default.
- W3124202226 hasAuthorship W3124202226A5085662800 @default.
- W3124202226 hasConcept C118792377 @default.
- W3124202226 hasConcept C134121241 @default.
- W3124202226 hasConcept C161790260 @default.
- W3124202226 hasConcept C178790620 @default.
- W3124202226 hasConcept C179104552 @default.
- W3124202226 hasConcept C185592680 @default.
- W3124202226 hasConcept C191897082 @default.
- W3124202226 hasConcept C192562407 @default.
- W3124202226 hasConcept C2779607525 @default.
- W3124202226 hasConcept C2779870537 @default.
- W3124202226 hasConcept C2780178953 @default.
- W3124202226 hasConcept C2780471494 @default.
- W3124202226 hasConcept C2781187707 @default.
- W3124202226 hasConcept C7082614 @default.