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- W3124327645 endingPage "2024" @default.
- W3124327645 startingPage "2016" @default.
- W3124327645 abstract "Stimuli-responsive structural transformations between discrete coordination supramolecular architectures not only are essential to construct smart functional materials but also provide a versatile molecular-level platform to mimic the biological transformation process. We report here the controlled self-assembly of three topologically unprecedented conjoined twin-cages, i.e., one stapled interlocked Pd12L6 cage (2) and two helically isomeric Pd6L3 cages (3 and 4) made from the same cis-blocked palladium corners and a new bis-bidentate ligand (1). While cage 2 features three mechanically coupled cavities, cages 3 and 4 are topologically isomeric helicate-based twin-cages based on the same metal/ligand stoichiometry. Sole formation of cage 2 or a dynamic mixture of cages 3 and 4 can be controlled by changing the solvents employed during the self-assembly. Structural conversions between cages 3 and 4 can be triggered by changes in both temperature/solvent and induced-fit guest encapsulations. Well-controlled interconversion between such topologically complex superstructures may lay a solid foundation for achieving a variety of functions within a switchable system." @default.
- W3124327645 created "2021-02-01" @default.
- W3124327645 creator A5007783109 @default.
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- W3124327645 creator A5089141991 @default.
- W3124327645 date "2021-01-20" @default.
- W3124327645 modified "2023-10-17" @default.
- W3124327645 title "Controlled Self-Assembly and Multistimuli-Responsive Interconversions of Three Conjoined Twin-Cages" @default.
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