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- W3124376098 abstract "The polymer binder, poly(imide-co-siloxane) (PIS), was synthesized and applied to form a thin cathode layer of composites for a thermal battery that has an unusually high operating temperature of 450 °C. The PIS was prepared through cross-linking of the polyimide with polysiloxane. The morphology of FeS2/PIS composites showed that FeS2 particles was coated with the PIS cross-linked gel. The FeS2/PIS composites enabled to fabricate mechanically stable thin cathode layer that was 10–20% of the thickness of a conventional pellet-type cathode. The FeS2/PIS composites were stable up to 400 °C and maintained their morphology at this temperature. PIS coating layers decomposed at 450 °C, and a new residue was generated, which was observed by transmission electron microscopy, and the compositional change was analyzed. The FeS2/PIS composites showed enhanced thermal stability over that of FeS2 in thermogravimetric analysis. The thermal battery with the PIS polymer binder showed a 20% discharge capacity increase when compared to a conventional pellet-type cathode." @default.
- W3124376098 created "2021-02-01" @default.
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- W3124376098 date "2018-11-14" @default.
- W3124376098 modified "2023-10-03" @default.
- W3124376098 title "Poly(imide-co-siloxane) as a Thermo-Stable Binder for a Thin Layer Cathode of Thermal Batteries" @default.
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- W3124376098 doi "https://doi.org/10.3390/en11113154" @default.
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