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- W3124426166 abstract "Abstract The fully fluorinated complex, Pd(L)2, comprised of one Pd2+ ion and two ligands, namely bis(pentafluorobenzoyl)methanido− (L), was well crystallized with mesitylene (C9H12) and p-xylene (C8H10) as guest molecules to form unique co-crystals, Pd(L)2·2C9H12 and Pd(L)2·2C8H10, respectively, using a chloroform or ethyl acetate solution. In the crystals, the π-planes of the guest molecules closely interacted with the pentafluorophenyl groups of the complex through an π···π-hole interaction. By the combination of two guest molecules, a new crystal, Pd(L)2·2C9H12·C8H10, was obtained and two mesitylene and one p-xylene molecules are quantitatively inserted into the crystal without any structural disorder, showing the good affinity of the guest molecules and the flexible shape changes of the complex." @default.
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- W3124426166 date "2021-03-01" @default.
- W3124426166 modified "2023-09-27" @default.
- W3124426166 title "Co-crystal structures and Hirshfeld surface analysis of mesitylene and/or p-xylene solvated pseudopolymorphs of fully fluorinated Pd(II) complex" @default.
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- W3124426166 doi "https://doi.org/10.1016/j.poly.2021.115035" @default.
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