FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3124536064> ?p ?o ?g. }

• W3124536064 endingPage "2055" @default.
• W3124536064 startingPage "2045" @default.
• W3124536064 abstract "Bis(formazanate)iron(II) complexes undergo a thermally induced S = 0 to S = 2 spin transition in solution. Here we present a study of how steric effects and π-stacking interactions between the triarylformazanate ligands affect the spin-crossover behavior, in addition to electronic substituent effects. Moreover, the effect of increasing the denticity of the formazanate ligands is explored by including additional OMe donors in the ligand (7). In total, six new compounds (2–7) have been synthesized and characterized, both in solution and in the solid state, via spectroscopic, magnetic, and structural analyses. The series spans a broad range of spin-crossover temperatures (T1/2) for the LS ⇌ HS equilibrium in solution, with the exception of compound 6 which remains high-spin (S = 2) down to 210 K. In the solid state, 6 was shown to exist in two distinct forms: a tetrahedral high-spin complex (6a, S = 2) and a rare square-planar structure with an intermediate-spin state (6b, S = 1). SQUID measurements, 57Fe Mössbauer spectroscopy, and differential scanning calorimetry indicate that in the solid state the square-planar form 6b undergoes an incomplete spin-change-coupled isomerization to tetrahedral 6a. The complex that contains additional OMe donors (7) results in a six-coordinate (NNO)2Fe coordination geometry, which shifts the spin-crossover to significantly higher temperatures (T1/2 = 444 K). The available experimental and computational data for 7 suggest that the Fe···OMe interaction is retained upon spin-crossover. Despite the difference in coordination environment, the weak OMe donors do not significantly alter the electronic structure or ligand-field splitting, and the occurrence of spin-crossover (similar to the compounds lacking the OMe groups) originates from a large degree of metal–ligand π-covalency." @default.
• W3124536064 created "2021-02-01" @default.
• W3124536064 creator A5012244806 @default.
• W3124536064 creator A5017975823 @default.
• W3124536064 creator A5032458511 @default.
• W3124536064 creator A5035643517 @default.
• W3124536064 creator A5038939814 @default.
• W3124536064 creator A5051370657 @default.
• W3124536064 creator A5080492950 @default.
• W3124536064 date "2021-01-19" @default.
• W3124536064 modified "2023-09-27" @default.
• W3124536064 title "Widening the Window of Spin-Crossover Temperatures in Bis(formazanate)iron(II) Complexes via Steric and Noncovalent Interactions" @default.
• W3124536064 cites W1969284792 @default.
• W3124536064 cites W1969360633 @default.
• W3124536064 cites W1983828847 @default.
• W3124536064 cites W1985127245 @default.
• W3124536064 cites W1987532154 @default.
• W3124536064 cites W1988081692 @default.
• W3124536064 cites W1988091937 @default.
• W3124536064 cites W1993505425 @default.
• W3124536064 cites W2003549711 @default.
• W3124536064 cites W2004019187 @default.
• W3124536064 cites W2008215843 @default.
• W3124536064 cites W2010396430 @default.
• W3124536064 cites W2028785018 @default.
• W3124536064 cites W2029591012 @default.
• W3124536064 cites W2032719166 @default.
• W3124536064 cites W2053068187 @default.
• W3124536064 cites W2053898708 @default.
• W3124536064 cites W2066023565 @default.
• W3124536064 cites W2075064996 @default.
• W3124536064 cites W2079935930 @default.
• W3124536064 cites W2080447728 @default.
• W3124536064 cites W2085819894 @default.
• W3124536064 cites W2086445382 @default.
• W3124536064 cites W2086579657 @default.
• W3124536064 cites W2086957099 @default.
• W3124536064 cites W2088677866 @default.
• W3124536064 cites W2092735963 @default.
• W3124536064 cites W2106424251 @default.
• W3124536064 cites W2115315764 @default.
• W3124536064 cites W2117569373 @default.
• W3124536064 cites W2126901416 @default.
• W3124536064 cites W2131350133 @default.
• W3124536064 cites W2143981217 @default.
• W3124536064 cites W2148651355 @default.
• W3124536064 cites W2153592438 @default.
• W3124536064 cites W2155038486 @default.
• W3124536064 cites W2155600484 @default.
• W3124536064 cites W2156337687 @default.
• W3124536064 cites W2313942694 @default.
• W3124536064 cites W2319933727 @default.
• W3124536064 cites W2322007817 @default.
• W3124536064 cites W2326385719 @default.
• W3124536064 cites W2330291315 @default.
• W3124536064 cites W2338378423 @default.
• W3124536064 cites W2340715265 @default.
• W3124536064 cites W2394384060 @default.
• W3124536064 cites W2497944204 @default.
• W3124536064 cites W2535444935 @default.
• W3124536064 cites W2553829951 @default.
• W3124536064 cites W2592137500 @default.
• W3124536064 cites W2808553317 @default.
• W3124536064 cites W2902085700 @default.
• W3124536064 cites W2942686846 @default.
• W3124536064 cites W2949436959 @default.
• W3124536064 cites W3101966839 @default.
• W3124536064 doi "https://doi.org/10.1021/acs.inorgchem.0c03593" @default.
• W3124536064 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7856632" @default.
• W3124536064 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33464882" @default.
• W3124536064 hasPublicationYear "2021" @default.
• W3124536064 type Work @default.
• W3124536064 sameAs 3124536064 @default.
• W3124536064 citedByCount "15" @default.
• W3124536064 countsByYear W31245360642021 @default.
• W3124536064 countsByYear W31245360642022 @default.
• W3124536064 countsByYear W31245360642023 @default.
• W3124536064 crossrefType "journal-article" @default.
• W3124536064 hasAuthorship W3124536064A5012244806 @default.
• W3124536064 hasAuthorship W3124536064A5017975823 @default.
• W3124536064 hasAuthorship W3124536064A5032458511 @default.
• W3124536064 hasAuthorship W3124536064A5035643517 @default.
• W3124536064 hasAuthorship W3124536064A5038939814 @default.
• W3124536064 hasAuthorship W3124536064A5051370657 @default.
• W3124536064 hasAuthorship W3124536064A5080492950 @default.
• W3124536064 hasBestOaLocation W31245360641 @default.
• W3124536064 hasConcept C115624301 @default.
• W3124536064 hasConcept C116569031 @default.
• W3124536064 hasConcept C127413603 @default.
• W3124536064 hasConcept C146978453 @default.
• W3124536064 hasConcept C170493617 @default.
• W3124536064 hasConcept C178516000 @default.
• W3124536064 hasConcept C178790620 @default.
• W3124536064 hasConcept C179104552 @default.
• W3124536064 hasConcept C185592680 @default.
• W3124536064 hasConcept C201194858 @default.
• W3124536064 hasConcept C2777222292 @default.
• W3124536064 hasConcept C2778689049 @default.

• next