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• W3124621928 abstract "A new method for the generation of benzyl radicals from acetals via low-valent titanium-mediated homolytic C–O bond cleavage is presented. The low cost and availability of the developed titanium reagent enable efficient access to α-alkoxy carbon radical species via the developed reaction. Benzyl radicals were generated from acetals via low-valent titanium-mediated homolytic C–O bond cleavage, and were subjected to radical conjugate addition. Owing to the low cost and availability of the developed titanium reagent, the methodology provides efficient access to α-alkoxy benzyl radical species. Unstable ketal substrates also afforded conjugate addition products in acceptable yields." @default.
• W3124621928 created "2021-02-01" @default.
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• W3124621928 date "2021-04-15" @default.
• W3124621928 modified "2023-09-27" @default.
• W3124621928 title "Conjugate Addition of Acetal-Derived Benzyl Radicals Generated from Low-Valent Titanium-Mediated C–O Bond Cleavage" @default.
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• W3124621928 doi "https://doi.org/10.1246/bcsj.20200364" @default.
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