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• W3124753679 abstract "We observe vibronic transitions in CaD+ between the 11Σ and 21Σ electronic states by resonance enhanced multiphoton photodissociation spectroscopy in a Coulomb crystal. The vibronic transitions are compared with previous measurements on CaH+. The result is a revised assignment of the CaH+ vibronic levels and a disagreement with multi-state-complete-active-space second-order perturbation theory theoretical calculations by approximately 700 cm−1. Updated high-level coupled-cluster calculations that include core-valence correlations reduce the disagreement between theory and experiment to 300 cm−1." @default.
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• W3124753679 date "2017-12-06" @default.
• W3124753679 modified "2023-10-14" @default.
• W3124753679 title "Reassigning the CaH⁺ 1¹Σ → 2¹Σ vibronic transition with CaD⁺" @default.
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• W3124753679 doi "https://doi.org/10.1063/1.5016556" @default.
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