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- W3124809145 abstract "Abstract Comparison of various organic compounds such as glycols, amines and alkanolamines as organocatalysts in amidation of fatty acid methyl esters with 3‐(dimethylamino)‐1‐propylamine was made for the first time. It was experimentally detected that catalysts containing OH‐groups (alcohols, glycols, glycerol and aminoalcohols) influence the reaction rate. Moreover, catalytic effect is depending on the catalysts geometry significantly. 1,5‐diols (e. g. diethylene glycol and diethanolamine) were found to accelerate the reaction more than other OH‐groups containing additives. It was supposed, that this catalytic effect is caused by specific associative interactions between reactants and 1,5‐diols, what was confirmed by quantum mechanics calculations. Catalysts concentration effects on the reaction rate were also investigated." @default.
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- W3124809145 date "2021-01-19" @default.
- W3124809145 modified "2023-09-26" @default.
- W3124809145 title "Specific Organocatalysis in Amidation Reaction of Fatty Acid Methyl Esters with 3‐(Dimethylamino)‐1‐propylamine" @default.
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- W3124809145 doi "https://doi.org/10.1002/slct.202003197" @default.
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