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- W3124880913 abstract "Supramol. polymers form a new class of polymers in which the reversibility of the non-covalent bonds between the monomers gives rise to interesting material properties. Ureido-pyrimidinone mols. strongly dimerize via quadruple hydrogen bonds and bi-functional derivs. form polymers or cyclic structures depending on the pre-organization of the linker and external conditions such as concn. and temp. Bi-functional ureido-pyrimidinone mols. with a meta-phenylene linker aggregate into hexameric cycles, due to pre-organization of the phenylene linker. SANS, viscosity and NMR-diffusion measurements showed that the hexameric cycles self-assemble into cylindrical aggregates, with solvent, concn. and temp. dependent length. These cylindrical aggregates may be used as scaffolds for thermoplastic elastomers, in which the cylinders form the hard-block and the polymer the soft-block. [on SciFinder (R)]" @default.
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- W3124880913 date "2003-01-01" @default.
- W3124880913 modified "2023-09-27" @default.
- W3124880913 title "Hexameric cycles from hydrogen-bonded ureido-pyrimidinones" @default.
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