Matches in SemOpenAlex for { <https://semopenalex.org/work/W3125097112> ?p ?o ?g. }
- W3125097112 endingPage "125" @default.
- W3125097112 startingPage "116" @default.
- W3125097112 abstract "Three distinct four-component supramolecular nanorotors were prepared, using, for the first time, bipyridine instead of phenanthroline stations in the stator. Following our established self-sorting protocol to multicomponent nanodevices, the nanorotors were self-assembled by mixing the stator, rotators with various pyridine head groups, copper(I) ions and 1,4-diazabicyclo[2.2.2]octane (DABCO). Whereas the exchange of a phenanthroline vs. a bipyridine station did not entail significant changes in the rotational exchange frequency, the para-substituents at the pyridine head group of the rotator had drastic consequences on the speed: 4-OMe (k298 = 35 kHz), 4-H (k298 = 77 kHz) and 4-NO2 (k298 = 843 kHz). The exchange frequency (log k) showed an excellent linear correlation with both the Hammett substituent constants and log K of the copper(I)–ligand interaction, proving that rotator–copper(I) bond cleavage is the key determining factor in the rate-determining step." @default.
- W3125097112 created "2021-02-01" @default.
- W3125097112 creator A5005515797 @default.
- W3125097112 creator A5021980185 @default.
- W3125097112 creator A5051082150 @default.
- W3125097112 creator A5064171182 @default.
- W3125097112 creator A5067301238 @default.
- W3125097112 date "2021-01-22" @default.
- W3125097112 modified "2023-10-17" @default.
- W3125097112 title "Exchange Speed of Four-Component Nanorotors Correlates with Hammett Substituent Constants" @default.
- W3125097112 cites W104838432 @default.
- W3125097112 cites W1489326505 @default.
- W3125097112 cites W1497035718 @default.
- W3125097112 cites W1557552990 @default.
- W3125097112 cites W1966024523 @default.
- W3125097112 cites W1967040140 @default.
- W3125097112 cites W1967691340 @default.
- W3125097112 cites W1968345212 @default.
- W3125097112 cites W1990247029 @default.
- W3125097112 cites W1991632645 @default.
- W3125097112 cites W2003826528 @default.
- W3125097112 cites W2010945002 @default.
- W3125097112 cites W2011100922 @default.
- W3125097112 cites W2023186508 @default.
- W3125097112 cites W2044496967 @default.
- W3125097112 cites W2045251905 @default.
- W3125097112 cites W2057980421 @default.
- W3125097112 cites W2058387389 @default.
- W3125097112 cites W2070269629 @default.
- W3125097112 cites W2071397131 @default.
- W3125097112 cites W2083067327 @default.
- W3125097112 cites W2103390877 @default.
- W3125097112 cites W2116747597 @default.
- W3125097112 cites W2145329069 @default.
- W3125097112 cites W2150060017 @default.
- W3125097112 cites W2169954828 @default.
- W3125097112 cites W2228242821 @default.
- W3125097112 cites W2285865929 @default.
- W3125097112 cites W2318002669 @default.
- W3125097112 cites W2318613819 @default.
- W3125097112 cites W2322006467 @default.
- W3125097112 cites W2442177838 @default.
- W3125097112 cites W2519642042 @default.
- W3125097112 cites W2605768989 @default.
- W3125097112 cites W2615198142 @default.
- W3125097112 cites W2727562423 @default.
- W3125097112 cites W2759294786 @default.
- W3125097112 cites W2765491844 @default.
- W3125097112 cites W2801882715 @default.
- W3125097112 cites W2804300132 @default.
- W3125097112 cites W2809136712 @default.
- W3125097112 cites W2884339683 @default.
- W3125097112 cites W2918166876 @default.
- W3125097112 cites W2969168646 @default.
- W3125097112 cites W2982287132 @default.
- W3125097112 cites W2996232687 @default.
- W3125097112 cites W3015588931 @default.
- W3125097112 cites W3030872793 @default.
- W3125097112 cites W4211203651 @default.
- W3125097112 doi "https://doi.org/10.3390/chemistry3010009" @default.
- W3125097112 hasPublicationYear "2021" @default.
- W3125097112 type Work @default.
- W3125097112 sameAs 3125097112 @default.
- W3125097112 citedByCount "3" @default.
- W3125097112 countsByYear W31250971122022 @default.
- W3125097112 crossrefType "journal-article" @default.
- W3125097112 hasAuthorship W3125097112A5005515797 @default.
- W3125097112 hasAuthorship W3125097112A5021980185 @default.
- W3125097112 hasAuthorship W3125097112A5051082150 @default.
- W3125097112 hasAuthorship W3125097112A5064171182 @default.
- W3125097112 hasAuthorship W3125097112A5067301238 @default.
- W3125097112 hasBestOaLocation W31250971121 @default.
- W3125097112 hasConcept C115624301 @default.
- W3125097112 hasConcept C121332964 @default.
- W3125097112 hasConcept C147597530 @default.
- W3125097112 hasConcept C148898269 @default.
- W3125097112 hasConcept C155647269 @default.
- W3125097112 hasConcept C178790620 @default.
- W3125097112 hasConcept C185592680 @default.
- W3125097112 hasConcept C2775995839 @default.
- W3125097112 hasConcept C2776624427 @default.
- W3125097112 hasConcept C2777660389 @default.
- W3125097112 hasConcept C2778689049 @default.
- W3125097112 hasConcept C2779336533 @default.
- W3125097112 hasConcept C2779485729 @default.
- W3125097112 hasConcept C544778455 @default.
- W3125097112 hasConcept C62520636 @default.
- W3125097112 hasConcept C71240020 @default.
- W3125097112 hasConcept C8010536 @default.
- W3125097112 hasConcept C8503813 @default.
- W3125097112 hasConcept C93275456 @default.
- W3125097112 hasConcept C93391505 @default.
- W3125097112 hasConceptScore W3125097112C115624301 @default.
- W3125097112 hasConceptScore W3125097112C121332964 @default.
- W3125097112 hasConceptScore W3125097112C147597530 @default.
- W3125097112 hasConceptScore W3125097112C148898269 @default.
- W3125097112 hasConceptScore W3125097112C155647269 @default.
- W3125097112 hasConceptScore W3125097112C178790620 @default.