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- W3125457979 abstract "δ-Valerolactone derivatives are formed by cyanide-catalyzed ring-transformation of cyclic α-hydroxy-β-oxoesters. This unprecedented reaction defines a new synthetic methodology, and the products are obtained in up to quantitative yields. Several alkyl substitutions as well as different ester residues are tolerated. Furthermore, benzo- and heteroarene-annulated starting materials are converted without problems. As an additional benefit, the starting materials are straightforwardly accessed by cerium-catalyzed aerobic α-hydroxylation of readily available β-oxoesters." @default.
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- W3125457979 date "2021-01-19" @default.
- W3125457979 modified "2023-10-16" @default.
- W3125457979 title "Formation of δ-Lactones by Cyanide Catalyzed Rearrangement of α-Hydroxy-β-oxoesters" @default.
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- W3125457979 doi "https://doi.org/10.1021/acs.orglett.0c04157" @default.
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