Matches in SemOpenAlex for { <https://semopenalex.org/work/W3125492704> ?p ?o ?g. }
- W3125492704 abstract "Abstract The semiclassical models of nonadiabatic transition were proposed first by Landau and Zener in 1932, and have been widely used in the study of electron transfer (ET); however, experimental demonstration of the Landau-Zener formula remains challenging to observe. Herein, employing the Hush-Marcus theory, thermal ET in mixed-valence complexes {[Mo 2 ]-(ph) n -[Mo 2 ]} + ( n = 1–3) has been investigated, spanning the nonadiabatic throughout the adiabatic limit, by analysis of the intervalence transition absorbances. Evidently, the Landau-Zener formula is valid in the adiabatic regime in a broader range of conditions than the theoretical limitation known as the narrow avoided-crossing. The intermediate system is identified with an overall transition probability (κ el ) of ∼0.5, which is contributed by the single and the first multiple passage. This study shows that in the intermediate regime, the ET kinetic results derived from the adiabatic and nonadiabatic formalisms are nearly identical, in accordance with the Landau-Zener model. The obtained insights help to understand and control the ET processes in biological and chemical systems." @default.
- W3125492704 created "2021-02-01" @default.
- W3125492704 creator A5006697209 @default.
- W3125492704 creator A5015628426 @default.
- W3125492704 creator A5019567696 @default.
- W3125492704 creator A5033101046 @default.
- W3125492704 creator A5038645349 @default.
- W3125492704 creator A5042785839 @default.
- W3125492704 creator A5058242512 @default.
- W3125492704 creator A5073987380 @default.
- W3125492704 creator A5074275434 @default.
- W3125492704 creator A5080840986 @default.
- W3125492704 creator A5088432822 @default.
- W3125492704 creator A5089023194 @default.
- W3125492704 date "2021-01-19" @default.
- W3125492704 modified "2023-10-16" @default.
- W3125492704 title "Crossover between the adiabatic and nonadiabatic electron transfer limits in the Landau-Zener model" @default.
- W3125492704 cites W1675570769 @default.
- W3125492704 cites W1963905759 @default.
- W3125492704 cites W1966624508 @default.
- W3125492704 cites W1979336299 @default.
- W3125492704 cites W1981659415 @default.
- W3125492704 cites W1982654570 @default.
- W3125492704 cites W1985075289 @default.
- W3125492704 cites W1994570180 @default.
- W3125492704 cites W1996718955 @default.
- W3125492704 cites W2001270915 @default.
- W3125492704 cites W2005197716 @default.
- W3125492704 cites W2006264911 @default.
- W3125492704 cites W2016090732 @default.
- W3125492704 cites W2016592851 @default.
- W3125492704 cites W2022205840 @default.
- W3125492704 cites W2028201857 @default.
- W3125492704 cites W2031904472 @default.
- W3125492704 cites W2032587009 @default.
- W3125492704 cites W2034402791 @default.
- W3125492704 cites W2044931258 @default.
- W3125492704 cites W2055507709 @default.
- W3125492704 cites W2073006389 @default.
- W3125492704 cites W2076004384 @default.
- W3125492704 cites W2081337977 @default.
- W3125492704 cites W2089605181 @default.
- W3125492704 cites W2093478000 @default.
- W3125492704 cites W2093810900 @default.
- W3125492704 cites W2105510993 @default.
- W3125492704 cites W2113274671 @default.
- W3125492704 cites W2138289499 @default.
- W3125492704 cites W2153754246 @default.
- W3125492704 cites W2157327418 @default.
- W3125492704 cites W2158046987 @default.
- W3125492704 cites W2316618673 @default.
- W3125492704 cites W2321239885 @default.
- W3125492704 cites W2328701768 @default.
- W3125492704 cites W2491861284 @default.
- W3125492704 cites W2770481178 @default.
- W3125492704 cites W2931103182 @default.
- W3125492704 cites W642437637 @default.
- W3125492704 doi "https://doi.org/10.1038/s41467-020-20557-7" @default.
- W3125492704 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7815917" @default.
- W3125492704 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33469004" @default.
- W3125492704 hasPublicationYear "2021" @default.
- W3125492704 type Work @default.
- W3125492704 sameAs 3125492704 @default.
- W3125492704 citedByCount "15" @default.
- W3125492704 countsByYear W31254927042021 @default.
- W3125492704 countsByYear W31254927042022 @default.
- W3125492704 countsByYear W31254927042023 @default.
- W3125492704 crossrefType "journal-article" @default.
- W3125492704 hasAuthorship W3125492704A5006697209 @default.
- W3125492704 hasAuthorship W3125492704A5015628426 @default.
- W3125492704 hasAuthorship W3125492704A5019567696 @default.
- W3125492704 hasAuthorship W3125492704A5033101046 @default.
- W3125492704 hasAuthorship W3125492704A5038645349 @default.
- W3125492704 hasAuthorship W3125492704A5042785839 @default.
- W3125492704 hasAuthorship W3125492704A5058242512 @default.
- W3125492704 hasAuthorship W3125492704A5073987380 @default.
- W3125492704 hasAuthorship W3125492704A5074275434 @default.
- W3125492704 hasAuthorship W3125492704A5080840986 @default.
- W3125492704 hasAuthorship W3125492704A5088432822 @default.
- W3125492704 hasAuthorship W3125492704A5089023194 @default.
- W3125492704 hasBestOaLocation W31254927041 @default.
- W3125492704 hasConcept C109663097 @default.
- W3125492704 hasConcept C121332964 @default.
- W3125492704 hasConcept C122507166 @default.
- W3125492704 hasConcept C137488568 @default.
- W3125492704 hasConcept C154945302 @default.
- W3125492704 hasConcept C165801399 @default.
- W3125492704 hasConcept C185592680 @default.
- W3125492704 hasConcept C26873012 @default.
- W3125492704 hasConcept C41008148 @default.
- W3125492704 hasConcept C50566616 @default.
- W3125492704 hasConcept C535169671 @default.
- W3125492704 hasConcept C62520636 @default.
- W3125492704 hasConcept C84114770 @default.
- W3125492704 hasConceptScore W3125492704C109663097 @default.
- W3125492704 hasConceptScore W3125492704C121332964 @default.
- W3125492704 hasConceptScore W3125492704C122507166 @default.
- W3125492704 hasConceptScore W3125492704C137488568 @default.
- W3125492704 hasConceptScore W3125492704C154945302 @default.
- W3125492704 hasConceptScore W3125492704C165801399 @default.