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- W3125997918 endingPage "3500" @default.
- W3125997918 startingPage "3496" @default.
- W3125997918 abstract "Abstract α‐Haloboronates are useful organic synthons that can be converted to a diverse array of α‐substituted alkyl borons. Methods to α‐haloboronates are limiting and often suffer from harsh reaction conditions. Reported herein is a photochemical radical C‐H halogenation of benzyl N ‐methyliminodiacetyl (MIDA) boronates. Fluorination, chlorination, and bromination reactions were effective by using this protocol. Upon reaction with different nucleophiles, the C−Br bond in the brominated product could be readily transformed to a series of C−C, C−O, C−N, C−S, C−P, and C−I bonds, some of which are difficult to forge with α‐halo sp 2 ‐B boronate esters. An activation effect of B(MIDA) moiety was found." @default.
- W3125997918 created "2021-02-01" @default.
- W3125997918 creator A5017464022 @default.
- W3125997918 creator A5042257471 @default.
- W3125997918 creator A5045152683 @default.
- W3125997918 creator A5060562691 @default.
- W3125997918 creator A5067746639 @default.
- W3125997918 creator A5081906849 @default.
- W3125997918 creator A5083035909 @default.
- W3125997918 creator A5089807416 @default.
- W3125997918 date "2020-12-15" @default.
- W3125997918 modified "2023-09-25" @default.
- W3125997918 title "Photochemical Radical C–H Halogenation of Benzyl N‐Methyliminodiacetyl (MIDA) Boronates: Synthesis of α‐Functionalized Alkyl Boronates" @default.
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