FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3126223586> ?p ?o ?g. }

• W3126223586 endingPage "2016" @default.
• W3126223586 startingPage "2005" @default.
• W3126223586 abstract "Abstract CO 2 insertion reactions on terminal epoxides (styrene oxide, 1,2‐epoxyhexane and butyl glycidyl ether) were performed in a binary homogeneous mixture comprising NaBr as the nucleophilic catalyst and diethylene glycol (DEG) as both solvent and catalyst activator (cation coordinating agent). The reaction protocol was initially studied under batch conditions either in autoclaves and glass reactors: quantitative formation of the cyclic organic carbonate products (COCs) were achieved at T=100 °C and p 0 (CO 2 )=1–40 bar. The process was then transferred to continuous‐flow (CF) mode. The effects of the reaction parameters (T, p (CO 2 ), catalyst loading, and flow rates) were studied using microfluidic reactors of capacities variable from 7.85 ⋅ 10 −2 to 0.157 cm 3 . Albeit the CF reaction took place at T=220 °C and 120 bar, CF improved the productivity and allowed catalyst recycle through a semi‐continuous extraction procedure. For the model case of 1,2‐epoxyhexane, the (non‐optimized) rate of formation of the corresponding carbonate, 4‐butyl‐1,3‐dioxolan‐2‐one, was increased up to 27.6 mmol h −1 equiv. −1 , a value 2.5 higher than in the batch mode. Moreover, the NaBr/DEG mixture was reusable without loss of performance for at least 4 subsequent CF‐tests." @default.
• W3126223586 created "2021-02-15" @default.
• W3126223586 creator A5008471111 @default.
• W3126223586 creator A5020215265 @default.
• W3126223586 creator A5048020885 @default.
• W3126223586 creator A5056186703 @default.
• W3126223586 creator A5057003469 @default.
• W3126223586 date "2021-02-23" @default.
• W3126223586 modified "2023-10-03" @default.
• W3126223586 title "Diethylene Glycol/NaBr Catalyzed CO₂ Insertion into Terminal Epoxides: From Batch to Continuous Flow" @default.
• W3126223586 cites W155481722 @default.
• W3126223586 cites W2007970441 @default.
• W3126223586 cites W2035559468 @default.
• W3126223586 cites W2075449400 @default.
• W3126223586 cites W2077771216 @default.
• W3126223586 cites W2094413778 @default.
• W3126223586 cites W2104589843 @default.
• W3126223586 cites W2105634484 @default.
• W3126223586 cites W2112473180 @default.
• W3126223586 cites W2118257359 @default.
• W3126223586 cites W2135563100 @default.
• W3126223586 cites W2144186364 @default.
• W3126223586 cites W2151069716 @default.
• W3126223586 cites W2161128577 @default.
• W3126223586 cites W2313679818 @default.
• W3126223586 cites W2316098650 @default.
• W3126223586 cites W2322788072 @default.
• W3126223586 cites W2331053972 @default.
• W3126223586 cites W2331198214 @default.
• W3126223586 cites W2344429133 @default.
• W3126223586 cites W2345700910 @default.
• W3126223586 cites W2397648146 @default.
• W3126223586 cites W2583846105 @default.
• W3126223586 cites W2591811175 @default.
• W3126223586 cites W2609333415 @default.
• W3126223586 cites W2621108245 @default.
• W3126223586 cites W2623520619 @default.
• W3126223586 cites W2735571110 @default.
• W3126223586 cites W2771222095 @default.
• W3126223586 cites W2783296475 @default.
• W3126223586 cites W2783576632 @default.
• W3126223586 cites W2794199059 @default.
• W3126223586 cites W2806086620 @default.
• W3126223586 cites W2884691132 @default.
• W3126223586 cites W2886133549 @default.
• W3126223586 cites W2900894494 @default.
• W3126223586 cites W2902154532 @default.
• W3126223586 cites W2908169377 @default.
• W3126223586 cites W2914115933 @default.
• W3126223586 cites W2928430351 @default.
• W3126223586 cites W2953026345 @default.
• W3126223586 cites W2981727270 @default.
• W3126223586 cites W3041373173 @default.
• W3126223586 cites W3046527698 @default.
• W3126223586 cites W3046952915 @default.
• W3126223586 cites W4241029985 @default.
• W3126223586 cites W656294911 @default.
• W3126223586 doi "https://doi.org/10.1002/cctc.202002010" @default.
• W3126223586 hasPublicationYear "2021" @default.
• W3126223586 type Work @default.
• W3126223586 sameAs 3126223586 @default.
• W3126223586 citedByCount "10" @default.
• W3126223586 countsByYear W31262235862022 @default.
• W3126223586 countsByYear W31262235862023 @default.
• W3126223586 crossrefType "journal-article" @default.
• W3126223586 hasAuthorship W3126223586A5008471111 @default.
• W3126223586 hasAuthorship W3126223586A5020215265 @default.
• W3126223586 hasAuthorship W3126223586A5048020885 @default.
• W3126223586 hasAuthorship W3126223586A5056186703 @default.
• W3126223586 hasAuthorship W3126223586A5057003469 @default.
• W3126223586 hasBestOaLocation W31262235862 @default.
• W3126223586 hasConcept C13965031 @default.
• W3126223586 hasConcept C161790260 @default.
• W3126223586 hasConcept C178790620 @default.
• W3126223586 hasConcept C185592680 @default.
• W3126223586 hasConcept C2777516009 @default.
• W3126223586 hasConcept C2779136216 @default.
• W3126223586 hasConceptScore W3126223586C13965031 @default.
• W3126223586 hasConceptScore W3126223586C161790260 @default.
• W3126223586 hasConceptScore W3126223586C178790620 @default.
• W3126223586 hasConceptScore W3126223586C185592680 @default.
• W3126223586 hasConceptScore W3126223586C2777516009 @default.
• W3126223586 hasConceptScore W3126223586C2779136216 @default.
• W3126223586 hasIssue "8" @default.
• W3126223586 hasLocation W31262235861 @default.
• W3126223586 hasLocation W31262235862 @default.
• W3126223586 hasOpenAccess W3126223586 @default.
• W3126223586 hasPrimaryLocation W31262235861 @default.
• W3126223586 hasRelatedWork W2041180954 @default.
• W3126223586 hasRelatedWork W2067123306 @default.
• W3126223586 hasRelatedWork W218277662 @default.
• W3126223586 hasRelatedWork W2348615702 @default.
• W3126223586 hasRelatedWork W2363496820 @default.
• W3126223586 hasRelatedWork W2383036295 @default.
• W3126223586 hasRelatedWork W2976239633 @default.
• W3126223586 hasRelatedWork W3008848378 @default.
• W3126223586 hasRelatedWork W3036497132 @default.
• W3126223586 hasRelatedWork W4384163819 @default.

• next