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- W3126679551 abstract "In this study, we successfully synthesized two types of meso/microporous carbon materials through the carbonization and potassium hydroxide (KOH) activation for two different kinds of hyper-crosslinked polymers of TPE-CPOP1 and TPE-CPOP2, which were synthesized by using Friedel–Crafts reaction of tetraphenylethene (TPE) monomer with or without cyanuric chloride in the presence of AlCl3 as a catalyst. The resultant porous carbon materials exhibited the high specific area (up to 1100 m2 g−1), total pore volume, good thermal stability, and amorphous character based on thermogravimetric (TGA), N2 adsoprtion/desorption, and powder X-ray diffraction (PXRD) analyses. The as-prepared TPE-CPOP1 after thermal treatment at 800 °C (TPE-CPOP1-800) displayed excellent CO2 uptake performance (1.74 mmol g−1 at 298 K and 3.19 mmol g−1 at 273 K). Furthermore, this material possesses a high specific capacitance of 453 F g−1 at 5 mV s−1 comparable to others porous carbon materials with excellent columbic efficiencies for 10,000 cycle at 20 A g−1." @default.
- W3126679551 created "2021-02-15" @default.
- W3126679551 creator A5049323063 @default.
- W3126679551 creator A5053106100 @default.
- W3126679551 creator A5054357866 @default.
- W3126679551 creator A5055206891 @default.
- W3126679551 date "2021-01-31" @default.
- W3126679551 modified "2023-10-01" @default.
- W3126679551 title "Meso/Microporous Carbons from Conjugated Hyper-Crosslinked Polymers Based on Tetraphenylethene for High-Performance CO2 Capture and Supercapacitor" @default.
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- W3126679551 doi "https://doi.org/10.3390/molecules26030738" @default.
- W3126679551 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7866987" @default.
- W3126679551 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33572605" @default.
- W3126679551 hasPublicationYear "2021" @default.
- W3126679551 type Work @default.