FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3126809503> ?p ?o ?g. }

• W3126809503 endingPage "1869" @default.
• W3126809503 startingPage "1859" @default.
• W3126809503 abstract "Entanglements in polyelectrolyte solutions are a controversial issue in polymer science. Experimental studies during the last 20 years have raised doubts about the applicability of the concept of entanglements developed for neutral polymers to polyelectrolytes. To address this issue, we develop an approach based on the scaling relationship between the solution correlation length ξ = lgν/B and the number of monomers per correlation blob g for polymers with the monomer projection length l. The numerical coefficient B and exponent ν are determined by the solvent quality for the polymer backbone, chain Kuhn length, and type and strength of monomer–monomer interactions at different length scales starting from the solution correlation length down to electrostatic and thermal blob length scales. Values of the B parameters are obtained from plateaus of normalized specific viscosity ηsp(c)(cl3)α/Nw as a function of the monomer concentration c in different solution regimes of charged and neutral polymers with the weight average degree of polymerization Nw. The exponent α = 1/(1 – 3ν) describes the concentration dependence of the number of monomers per correlation blob, g ∼ cα. Knowledge of the B parameters allows calculations of crossover concentrations cD, cth, and c** into solutions of overlapping electrostatic and thermal blobs and concentrated polymer solutions, respectively. It is used for the universal representation of specific viscosity and relaxation time data in terms of the number of blobs per chain, Nw/g, which can be viewed as an effective chain degree of polymerization in polymer solutions. By applying this approach to viscosity data in the entangled solution regime, we obtain a packing number P̃e and a concentration dependence of the degree of polymerization between entanglements Ñe = P̃e2g, which include system dispersity information. This analysis shows that, in salt-free solutions of chains with degrees of polymerization of up to 104, polyelectrolytes only entangle in the solution regimes where the entanglement concentration ce > cD and solution properties are similar to those of neutral polymers. A similar conclusion is reached from analysis of viscosity data of polyelectrolytes in salt solutions. Therefore, in order to observe entanglements in polyelectrolyte solutions in a concentration range where their properties are controlled by electrostatic interactions, one has to study polyelectrolyte chains with degrees of polymerization of at least an order in magnitude longer than studied so far." @default.
• W3126809503 created "2021-02-15" @default.
• W3126809503 creator A5038537821 @default.
• W3126809503 creator A5066349059 @default.
• W3126809503 date "2021-02-01" @default.
• W3126809503 modified "2023-10-17" @default.
• W3126809503 title "When Do Polyelectrolytes Entangle?" @default.
• W3126809503 cites W1760605907 @default.
• W3126809503 cites W1966911176 @default.
• W3126809503 cites W1969414469 @default.
• W3126809503 cites W1986298959 @default.
• W3126809503 cites W1988087064 @default.
• W3126809503 cites W2000769681 @default.
• W3126809503 cites W2003642531 @default.
• W3126809503 cites W2004663802 @default.
• W3126809503 cites W2004930625 @default.
• W3126809503 cites W2010021338 @default.
• W3126809503 cites W2021506796 @default.
• W3126809503 cites W2027389228 @default.
• W3126809503 cites W2028275639 @default.
• W3126809503 cites W2036987776 @default.
• W3126809503 cites W2038066715 @default.
• W3126809503 cites W2039001412 @default.
• W3126809503 cites W2042990368 @default.
• W3126809503 cites W2045726017 @default.
• W3126809503 cites W2085116617 @default.
• W3126809503 cites W2088888471 @default.
• W3126809503 cites W2100669676 @default.
• W3126809503 cites W2140827982 @default.
• W3126809503 cites W2149102577 @default.
• W3126809503 cites W2159664510 @default.
• W3126809503 cites W2165923391 @default.
• W3126809503 cites W2562674550 @default.
• W3126809503 cites W2581853188 @default.
• W3126809503 cites W2797450813 @default.
• W3126809503 cites W2944960926 @default.
• W3126809503 cites W2962696403 @default.
• W3126809503 cites W2990322828 @default.
• W3126809503 cites W4211164027 @default.
• W3126809503 cites W4253240086 @default.
• W3126809503 doi "https://doi.org/10.1021/acs.macromol.0c02450" @default.
• W3126809503 hasPublicationYear "2021" @default.
• W3126809503 type Work @default.
• W3126809503 sameAs 3126809503 @default.
• W3126809503 citedByCount "20" @default.
• W3126809503 countsByYear W31268095032021 @default.
• W3126809503 countsByYear W31268095032022 @default.
• W3126809503 countsByYear W31268095032023 @default.
• W3126809503 crossrefType "journal-article" @default.
• W3126809503 hasAuthorship W3126809503A5038537821 @default.
• W3126809503 hasAuthorship W3126809503A5066349059 @default.
• W3126809503 hasConcept C11135259 @default.
• W3126809503 hasConcept C121332964 @default.
• W3126809503 hasConcept C127172972 @default.
• W3126809503 hasConcept C138885662 @default.
• W3126809503 hasConcept C153356533 @default.
• W3126809503 hasConcept C15744967 @default.
• W3126809503 hasConcept C159467904 @default.
• W3126809503 hasConcept C166940927 @default.
• W3126809503 hasConcept C178790620 @default.
• W3126809503 hasConcept C185592680 @default.
• W3126809503 hasConcept C188027245 @default.
• W3126809503 hasConcept C191516044 @default.
• W3126809503 hasConcept C192562407 @default.
• W3126809503 hasConcept C2524010 @default.
• W3126809503 hasConcept C26360006 @default.
• W3126809503 hasConcept C2776029896 @default.
• W3126809503 hasConcept C2780388253 @default.
• W3126809503 hasConcept C33923547 @default.
• W3126809503 hasConcept C41895202 @default.
• W3126809503 hasConcept C44228677 @default.
• W3126809503 hasConcept C521977710 @default.
• W3126809503 hasConcept C62520636 @default.
• W3126809503 hasConcept C77805123 @default.
• W3126809503 hasConcept C97355855 @default.
• W3126809503 hasConcept C99844830 @default.
• W3126809503 hasConceptScore W3126809503C11135259 @default.
• W3126809503 hasConceptScore W3126809503C121332964 @default.
• W3126809503 hasConceptScore W3126809503C127172972 @default.
• W3126809503 hasConceptScore W3126809503C138885662 @default.
• W3126809503 hasConceptScore W3126809503C153356533 @default.
• W3126809503 hasConceptScore W3126809503C15744967 @default.
• W3126809503 hasConceptScore W3126809503C159467904 @default.
• W3126809503 hasConceptScore W3126809503C166940927 @default.
• W3126809503 hasConceptScore W3126809503C178790620 @default.
• W3126809503 hasConceptScore W3126809503C185592680 @default.
• W3126809503 hasConceptScore W3126809503C188027245 @default.
• W3126809503 hasConceptScore W3126809503C191516044 @default.
• W3126809503 hasConceptScore W3126809503C192562407 @default.
• W3126809503 hasConceptScore W3126809503C2524010 @default.
• W3126809503 hasConceptScore W3126809503C26360006 @default.
• W3126809503 hasConceptScore W3126809503C2776029896 @default.
• W3126809503 hasConceptScore W3126809503C2780388253 @default.
• W3126809503 hasConceptScore W3126809503C33923547 @default.
• W3126809503 hasConceptScore W3126809503C41895202 @default.
• W3126809503 hasConceptScore W3126809503C44228677 @default.
• W3126809503 hasConceptScore W3126809503C521977710 @default.
• W3126809503 hasConceptScore W3126809503C62520636 @default.

• next