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- W3126870127 endingPage "154" @default.
- W3126870127 startingPage "103" @default.
- W3126870127 abstract "Propargylamines are a unique class of amine compounds that find broad applications in many fields of chemistry. The exceptional nature of propargylamines lies on the presence of an alkyne moiety and an amine group on the same chemical backbone, conferring both nucleophilic and electrophilic properties to these molecules at the same time. This peculiar characteristic makes propargylamines ideal substrates for the synthesis of a variety of organic compounds, especially heterocycles such as pyrroles, pyridines, quinolines, thia/oxazoles, and others. Because of their versatility and wide use in organic synthesis, a number of methodologies have been developed in the past decades, in particular to access chiral propargylamines in enantiomerically pure form. This chapter describes the recent advances made in the past few years in the asymmetric synthesis of chiral propargylamines. Metal-catalyzed approaches as well as more recent “greener” methodologies exploiting biocatalysis, photoredox catalysis, and organocatalysis are presented. The second part of the chapter is focused on some key transformations of propargylamines into useful heterocyclic compounds, with the aim to further highlight their versatility and utility in organic chemistry." @default.
- W3126870127 created "2021-02-15" @default.
- W3126870127 creator A5005498458 @default.
- W3126870127 creator A5026461992 @default.
- W3126870127 creator A5060141149 @default.
- W3126870127 date "2021-02-05" @default.
- W3126870127 modified "2023-09-26" @default.
- W3126870127 title "Propargylamines: Recent Advances in Asymmetric Synthesis and Use as Chemical Tools in Organic Chemistry" @default.
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