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- W3126943579 abstract "Nanoclusters, with their ultrasmall sizes, have emerged as an indispensable tool in designing structural materials with a wide range of applications, but predicting the synthesis mechanism and structures remains challenging. This work delineates a synthesis mechanism of gold nanoclusters (AuNCs), which is realized by functionalizing a wool keratin (WK) and silk fibroin (SF) resilience network structure via self-assembly with controllable microstructure transformation. We synthesized such AuNCs by reducing the thiol groups of WK into WK@AuNCs and then entering the WF&SF resilience framework during the reconstruction, achieving WK@AuNCs/WK&SF with high fluorescence intensity for selective quenching of heavy metal Cu 2+ ions. Further investigation indicated that α-helix and β-crystallites resulted in a soft–hard molecular segment denoted as WK&SF resilience network, which held and separated the WK@AuNCs into the nanocages. Owing to the synergism of these features, WK@AuNCs/WK&SF displayed superior fluorescence performances compared with WK@AuNCs." @default.
- W3126943579 created "2021-02-15" @default.
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- W3126943579 date "2021-01-28" @default.
- W3126943579 modified "2023-09-27" @default.
- W3126943579 title "Using Cu<sup>2+</sup> ions as a detection material to verify the synthesis mechanism of Au nanoclusters mediated by wool keratin and silk fibroin resilience network" @default.
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- W3126943579 doi "https://doi.org/10.1177/0040517521989775" @default.
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