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• W3127480997 abstract "The binding and stabilizing effect of arginine residues in certain aldolases served as inspiring source for the development of a family of amino acylguanidine organocatalysts. Screening and optimization led to identify the threonine derivative as the most suitable catalyst for the asymmetric aldol addition of hydroxyacetone, affording the syn diastereomer in high ee. In contrast, the proline derivative yielded the anti diasteromer. MMFF models suggest the presence of an extensive hydrogen bonding network between the acylguanidinium group and the reaction intermediates." @default.
• W3127480997 created "2021-02-15" @default.
• W3127480997 creator A5021142461 @default.
• W3127480997 date "2021-02-05" @default.
• W3127480997 modified "2023-09-26" @default.
• W3127480997 title "Amino Acylguanidines as Bioinspired Catalysts for the Asymmetric Aldol Reaction" @default.
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• W3127480997 doi "https://doi.org/10.3390/molecules26040826" @default.
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