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• W3127622013 abstract "In this contribution, we propose a new synthetic approach to tetrodotoxin (TTX), one of the most famous marine toxins that, after first preparing a functionalized linear substrate, forms a cyclohexane core from the substrate utilizing our mercuric triflate (Hg(OTf)2)-catalyzed cycloisomerization reaction. The concept was applied to the synthesis of 11-nor-6,7,8-trideoxyTTX and 11-nor-4,9-anhydro-6,7,8-trideoxyTTX, which are unnatural TTX analogues, demonstrating the validity of our new approach." @default.
• W3127622013 created "2021-02-15" @default.
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• W3127622013 date "2021-02-12" @default.
• W3127622013 modified "2023-09-25" @default.
• W3127622013 title "Tetrodotoxin Framework Construction from Linear Substrates Utilizing a Hg(OTf)₂-Catalyzed Cycloisomerization Reaction: Synthesis of the Unnatural Analogue 11-<i>nor</i>-6,7,8-Trideoxytetrodotoxin" @default.
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• W3127622013 doi "https://doi.org/10.1021/acs.orglett.1c00125" @default.
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