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- W3127628478 abstract "A single-component Co(-I) catalyst, [(PPh3)3Co(N2)]Li(THF)3, has been developed for olefin hydroarylations with (N-aryl)aryl imine substrates. More than 40 examples were examined under mild reaction conditions to afford the desired alkyl-arene product in good to excellent yields. Catalysis occurs in a regioselective manner to afford exclusively branched products with styrene-derived substrates or linear products for aliphatic olefins. Electron-withdrawing functional groups (e.g., -F, -CF3, and -CO2Me) were tolerated under the reaction conditions." @default.
- W3127628478 created "2021-02-15" @default.
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- W3127628478 date "2021-02-09" @default.
- W3127628478 modified "2023-10-14" @default.
- W3127628478 title "Olefin Hydroarylation Catalyzed by a Single-Component Cobalt(-I) Complex" @default.
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- W3127628478 doi "https://doi.org/10.1021/acs.orglett.1c00258" @default.
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