Matches in SemOpenAlex for { <https://semopenalex.org/work/W3127884561> ?p ?o ?g. }
- W3127884561 endingPage "121999" @default.
- W3127884561 startingPage "121999" @default.
- W3127884561 abstract "A series of high entropy alloy (HEA) hydrides/deuterides were synthesized and characterized to explore the relationship between thermal stability and the structure of TiZrHfMoNb deuterides. The X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry results reveal that the lattice constant and cell volume of TiZrHfMoNb hydrides increase with the increasing hydrogen content. The desorption temperature decreases with the increasing hydrogen content, indicating that the increased lattice constant arising from the introduction of deuterium atoms will destabilize the HEA deuterides. A density functional theory calculations demonstrate that the binding energies between hydrogen and metals in BCC TiZrHfMoNb hydrides decline with the increasing hydrogen content, meaning that the thermal stability decreases with the increasing hydrogen content. The HEA deuterides are found to be more stable than their hydrides, implying the remarkable isotopic effect of TiZrHfMoNb HEA. Neutron powder diffraction refinements confirm that deuterium atoms prefer to occupy both of the tetrahedral and octahedral interstitials in BCC structure, while a prior occupation of tetrahedral interstitial sites in FCC structure. The deuterium/hydrogen concentrations and the lattice constants are proposed to be the major factor regulating the thermal stability of HEA deuteride, making them suitable for different application field of hydrogen storage." @default.
- W3127884561 created "2021-02-15" @default.
- W3127884561 creator A5002337213 @default.
- W3127884561 creator A5003418091 @default.
- W3127884561 creator A5029573055 @default.
- W3127884561 creator A5033751081 @default.
- W3127884561 creator A5054161386 @default.
- W3127884561 creator A5056181916 @default.
- W3127884561 creator A5071718769 @default.
- W3127884561 creator A5079532032 @default.
- W3127884561 creator A5081645721 @default.
- W3127884561 creator A5084810994 @default.
- W3127884561 date "2021-05-01" @default.
- W3127884561 modified "2023-10-05" @default.
- W3127884561 title "Effects of deuterium content on the thermal stability and deuterium site occupancy of TiZrHfMoNb deuterides" @default.
- W3127884561 cites W1977687135 @default.
- W3127884561 cites W1980289182 @default.
- W3127884561 cites W1980885383 @default.
- W3127884561 cites W1981368803 @default.
- W3127884561 cites W1983814366 @default.
- W3127884561 cites W1988046851 @default.
- W3127884561 cites W1992025041 @default.
- W3127884561 cites W1995781421 @default.
- W3127884561 cites W2003975937 @default.
- W3127884561 cites W2012202321 @default.
- W3127884561 cites W2030976617 @default.
- W3127884561 cites W2049589864 @default.
- W3127884561 cites W2049639367 @default.
- W3127884561 cites W2057801653 @default.
- W3127884561 cites W2058085399 @default.
- W3127884561 cites W2073164239 @default.
- W3127884561 cites W2076053508 @default.
- W3127884561 cites W2077689930 @default.
- W3127884561 cites W2077956833 @default.
- W3127884561 cites W2079105963 @default.
- W3127884561 cites W2083222334 @default.
- W3127884561 cites W2083711490 @default.
- W3127884561 cites W2089814664 @default.
- W3127884561 cites W2230728100 @default.
- W3127884561 cites W2258281698 @default.
- W3127884561 cites W2495494698 @default.
- W3127884561 cites W2534691303 @default.
- W3127884561 cites W2549203060 @default.
- W3127884561 cites W2555775252 @default.
- W3127884561 cites W2565230774 @default.
- W3127884561 cites W2574350174 @default.
- W3127884561 cites W2585346090 @default.
- W3127884561 cites W2587258275 @default.
- W3127884561 cites W2605667488 @default.
- W3127884561 cites W2736309829 @default.
- W3127884561 cites W2743197473 @default.
- W3127884561 cites W2760973149 @default.
- W3127884561 cites W2763294544 @default.
- W3127884561 cites W2766610123 @default.
- W3127884561 cites W2772005373 @default.
- W3127884561 cites W2781700667 @default.
- W3127884561 cites W2786849367 @default.
- W3127884561 cites W2791269491 @default.
- W3127884561 cites W2801990953 @default.
- W3127884561 cites W2897761630 @default.
- W3127884561 cites W2903968731 @default.
- W3127884561 cites W2908017561 @default.
- W3127884561 cites W2914173910 @default.
- W3127884561 cites W2924278232 @default.
- W3127884561 cites W2942915186 @default.
- W3127884561 cites W2951225702 @default.
- W3127884561 cites W2969884925 @default.
- W3127884561 cites W2998766518 @default.
- W3127884561 cites W3007381406 @default.
- W3127884561 cites W3008165181 @default.
- W3127884561 cites W3110524175 @default.
- W3127884561 cites W3111257545 @default.
- W3127884561 doi "https://doi.org/10.1016/j.jssc.2021.121999" @default.
- W3127884561 hasPublicationYear "2021" @default.
- W3127884561 type Work @default.
- W3127884561 sameAs 3127884561 @default.
- W3127884561 citedByCount "4" @default.
- W3127884561 countsByYear W31278845612021 @default.
- W3127884561 countsByYear W31278845612022 @default.
- W3127884561 countsByYear W31278845612023 @default.
- W3127884561 crossrefType "journal-article" @default.
- W3127884561 hasAuthorship W3127884561A5002337213 @default.
- W3127884561 hasAuthorship W3127884561A5003418091 @default.
- W3127884561 hasAuthorship W3127884561A5029573055 @default.
- W3127884561 hasAuthorship W3127884561A5033751081 @default.
- W3127884561 hasAuthorship W3127884561A5054161386 @default.
- W3127884561 hasAuthorship W3127884561A5056181916 @default.
- W3127884561 hasAuthorship W3127884561A5071718769 @default.
- W3127884561 hasAuthorship W3127884561A5079532032 @default.
- W3127884561 hasAuthorship W3127884561A5081645721 @default.
- W3127884561 hasAuthorship W3127884561A5084810994 @default.
- W3127884561 hasConcept C113196181 @default.
- W3127884561 hasConcept C115624301 @default.
- W3127884561 hasConcept C120665830 @default.
- W3127884561 hasConcept C121332964 @default.
- W3127884561 hasConcept C132612359 @default.
- W3127884561 hasConcept C147789679 @default.
- W3127884561 hasConcept C178790620 @default.